{2-[(4-Bromophenyl)dimethylsilyl]phenyl}methanol synthesis

1synthesis methods

Product Name:{2-[(4-Bromophenyl)dimethylsilyl]phenyl}methanol
CAS Number:947515-73-3
Molecular formula:C15H17BrOSi
Molecular Weight:321.28

106-37-6 Synthesis

106-37-6
469 suppliers
$9.00/5g

1,1-DiMethyl-1,3-dihydrobenzo[c][1,2]oxasilole

321903-29-1
35 suppliers
$47.00/100mg

{2-[(4-Bromophenyl)dimethylsilyl]phenyl}methanol

947515-73-3
11 suppliers
$75.00/100mg

Yield:947515-73-3 91%

Reaction Conditions:

Stage #1: 1.4-dibromobenzenewith n-butyllithium in hexane at -78; for 2 h;
Stage #2: 1,1-dimethyl-1,3-dihydrobenzo[c][1,2]oxasilole in tetrahydrofuran;hexane at -78 - 20;Further stages.;

References:

Nakao, Yoshiaki;Chen, Jinshui;Imanaka, Hidekazu;Hiyama, Tamejiro;Ichikawa, Yoshitaka;Duan, Wei-Liang;Shintani, Ryo;Hayashi, Tamio [Journal of the American Chemical Society,2007,vol. 129,# 29,p. 9137 - 9143]