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ChemicalBook CAS DataBase List 2,6-Difluoro-N-methoxy-N-methylbenzamide
937601-82-6

2,6-Difluoro-N-methoxy-N-methylbenzamide synthesis

1synthesis methods
-

Yield:937601-82-6 96%

Reaction Conditions:

Stage #1: N,O-dimethylhydroxylamine*hydrochloridewith triethylamine in dichloromethane at 0;Inert atmosphere;
Stage #2: 2,6-difluorobenzoylchloride in dichloromethane at 0 - 20;Inert atmosphere;

References:

Kishore Kumar;Chavarria, Gustavo E.;Charlton-Sevcik, Amanda K.;Arispe, Wara M.;MacDonough, Matthew T.;Strecker, Tracy E.;Chen, Shen-En;Siim, Bronwyn G.;Chaplin, David J.;Trawick, Mary Lynn;Pinney, Kevin G. [Bioorganic and Medicinal Chemistry Letters,2010,vol. 20,# 4,p. 1415 - 1419] Location in patent:supporting information; experimental part

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