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2-methyl-3,3'-bipyridine synthesis

2synthesis methods
38749-79-0 Synthesis
3-Bromo-2-methylpyridine

38749-79-0
360 suppliers
$8.00/1g

329214-79-1 Synthesis
3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine

329214-79-1
239 suppliers
$6.00/1g

2-methyl-3,3'-bipyridine

1214326-04-1
6 suppliers
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Yield:1214326-04-1 81%

Reaction Conditions:

with potassium phosphate;(C5H5FeC5H3C(CH3)NC6H4CH3)PdCl(tricyclohexylphosphine);potassium acetate in 1,4-dioxane;water at 100; for 15 h;Inert atmosphere;Suzuki coupling;

References:

Wang, Lianhui;Cui, Xiuling;Li, Jingya;Wu, Yusheng;Zhu, Zhiwu;Wu, Yangjie [European Journal of Organic Chemistry,2012,# 3,p. 595 - 603] Location in patent:experimental part