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ChemicalBook CAS DataBase List 2-Morpholin-4-ylpyrimidin-5-amine
65735-68-4

2-Morpholin-4-ylpyrimidin-5-amine synthesis

2synthesis methods
-

Yield:65735-68-4 77%

Reaction Conditions:

with palladium 10% on activated carbon;hydrogen in ethanol at 25; for 16 h;

Steps:

63 Preparation of Compound 63-a

Under hydrogen (1 atm), to a solution of compound 63-b (350 mg, 1.67 mmol) in ethanol (10 mL) was added 10% Pd-C (0.1 g). The mixture was stirred at 25° C. for 16 hours, and then filtrated, the filtrate was concentrated under reduced pressure to give brown solid 63-a (230 mg, yield: 77%), which was used directly for the next step without purification. LC-MS (ESI): m/z=181 [M+H]+.

References:

US2015/336982,2015,A1 Location in patent:Paragraph 0396; 0398