![](/CAS/GIF/1203578-65-7.gif)
2-Phenyl-7-BroMoquinoline synthesis
- Product Name:2-Phenyl-7-BroMoquinoline
- CAS Number:1203578-65-7
- Molecular formula:C15H10BrN
- Molecular Weight:284.15
![2-AMINO-4-BROMOBENZYL ALCOHOL](/CAS/GIF/946122-05-0.gif)
946122-05-0
69 suppliers
$24.00/250mg
![Acetophenone](/CAS/GIF/98-86-2.gif)
98-86-2
743 suppliers
$9.00/5g
![2-Phenyl-7-BroMoquinoline](/CAS/GIF/1203578-65-7.gif)
1203578-65-7
53 suppliers
$45.00/10mg
Yield:1203578-65-7 94%
Reaction Conditions:
with [(η5-C5Me5)Ir(6,6'-dihydroxy-2,2'-bipyridine)(H2O)]OTf2;potassium hydroxide in water; for 12 h;Reflux;Green chemistry;
Steps:
24 7-bromo-2-phenylquinoline
Acetophenone (144 mg, 1.2 mmol),[Cp * Ir (6,6 '- (OH) 2bpy) (H2O)] [OTf] 2 (8.3mg, 0.01mmol, 1mol%), potassium hydroxide (56mg, 1.0mmol, 1.0 equiv.),2-Amino-4-bromobenzyl alcohol (201 mg, 1.0 mmol) and water (1 mL) were sequentially added to a 5 mL round bottom flask. After the reaction mixture was refluxed in air for 12 hours,Cool to room temperature. It was extracted with ethyl acetate, the solvent was removed by rotary evaporation and then purified by column chromatography (developing solvent: petroleum ether / acetic acidEthyl ester) to give the pure target compound in a yield of 94%
References:
CN107400084,2017,A Location in patent:Paragraph 0141; 0142; 0143
![2-AMINO-4-BROMOBENZALDEHYDE](/CAS/GIF/59278-65-8.gif)
59278-65-8
133 suppliers
$45.00/500mg
![Acetophenone](/CAS/GIF/98-86-2.gif)
98-86-2
743 suppliers
$9.00/5g
![2-Phenyl-7-BroMoquinoline](/CAS/GIF/1203578-65-7.gif)
1203578-65-7
53 suppliers
$45.00/10mg
![2-AMINO-4-BROMOBENZYL ALCOHOL](/CAS/GIF/946122-05-0.gif)
946122-05-0
69 suppliers
$24.00/250mg
![ALPHA-METHYLBENZYL ALCOHOL](/CAS/GIF/13323-81-4.gif)
13323-81-4
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![2-Phenyl-7-BroMoquinoline](/CAS/GIF/1203578-65-7.gif)
1203578-65-7
53 suppliers
$45.00/10mg
![2-AMINO-4-BROMOBENZYL ALCOHOL](/CAS/GIF/946122-05-0.gif)
946122-05-0
69 suppliers
$24.00/250mg
![(1-phenylethylideneamino) acetate](/CAS/20180601/GIF/19433-17-1.gif)
19433-17-1
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![2-Phenyl-7-BroMoquinoline](/CAS/GIF/1203578-65-7.gif)
1203578-65-7
53 suppliers
$45.00/10mg
![4-Bromo-2-nitrobenzaldehyde](/CAS/GIF/5551-12-2.gif)
5551-12-2
161 suppliers
$10.00/1g
![2,3-DIPHENYL-2,3-BUTANEDIOL](/CAS/GIF/1636-34-6.gif)
1636-34-6
35 suppliers
$26.00/250mg
![2-Phenyl-7-BroMoquinoline](/CAS/GIF/1203578-65-7.gif)
1203578-65-7
53 suppliers
$45.00/10mg