(3,3-dimethylbutyl)triethoxysilane synthesis

Yield:41966-94-3 99.7%

Reaction Conditions:

with N-heterocyclic carbene fuctionalized with methyl(trimethylsilane) and methoxypolyethylene glycol Pt(II) complex at 90; for 10 h;

Steps:

Catalysis hydrosilylation

General procedure: All the catalytic reactions were performed in a 10 mLat-bottomed tube without protection from air. The alkene(4.0 mmol) and the requisite amount of catalyst were placed ina dried tube and the reaction mixture was stirred for 5 min.Thereafter, the silane (4.4 mmol) was added and the resulting mixture was heated and stirred for the requisite time andthen cooled to room temperature. The product phase was separated by decantation and the alkene conversion and selectivity of the reaction were determined by GC-MS analysis on anAgilent 26890N/59731 apparatus equipped with a DB-5 column(30 m × 2.5 mm × 0.25 mm).

References:

Zhang, Fengxiang;Bai, Ying;Yang, Xiaoling;Li, Jiayun;Peng, Jianjian [Phosphorus, Sulfur and Silicon and the Related Elements,2017,vol. 192,# 12,p. 1271 - 1278]