ChemicalBook CAS DataBase List 3-ACETO-2-HYDROXYBIPHENYL

3-ACETO-2-HYDROXYBIPHENYL synthesis

10synthesis methods

Product Name:3-ACETO-2-HYDROXYBIPHENYL
CAS Number:21424-82-8
Molecular formula:C14H12O2
Molecular Weight:212.24

Preparation by Fries rearrangement of 2-acetoxybiphenyl with aluminium chloride,
without solvent between 130° and 160°
in boiling o-dichlorobenzene for 30 min (15%).

304-06-3
62 suppliers
$77.00/1g

917-54-4
172 suppliers
$52.10/25ml

21424-82-8
28 suppliers
$165.00/1g

Yield:21424-82-8 99%

Reaction Conditions:

in tetrahydrofuran at 0 - 20;Inert atmosphere;

References:

Ohmura, Toshimichi;Kusaka, Satoshi;Torigoe, Takeru;Suginome, Michinori [Advanced Synthesis and Catalysis,2019,vol. 361,# 19,p. 4448 - 4453] Location in patent:supporting information