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ChemicalBook CAS DataBase List 3-AMINO-N-(4-METHOXYPHENYL)BENZAMIDE
115175-19-4

3-AMINO-N-(4-METHOXYPHENYL)BENZAMIDE synthesis

3synthesis methods
101971-72-6 Synthesis
N-(4-Methoxyphenyl)-3-nitrobenzaMide, 97%

101971-72-6
4 suppliers
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Yield:115175-19-4 86%

Reaction Conditions:

with iron;ammonium chloride in methanol; for 7 h;Reflux;

Steps:

3.1.8. General Experimental Procedures of 4ii-8ii

General procedure: To a solution of 4i-8i (3.37 mmol) in methanol (20 mL) was added: ammonium chloride (doubleamounts of 4i-8i) and iron powder (6.03 mmol) and refluxed for 7 h. The reaction mixture wasevaporated to give an oily residue, which was added with water and extracted with dichloromethane(30 mL x 3). The combined organic phase was dried with anhydrous MgSO4, filtrated, and the filtratewas evaporated to yield a crude solid, which recrystallized with ethyl acetate and n-hexane to give apure white or pale yellow solid.

References:

Lee, Soo Hyun;Lee, Wonhwa;Bae, Jong-Sup;Ma, Eunsook [Molecules,2016,vol. 21,# 5,art. no. 676]