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ChemicalBook CAS DataBase List 3-Bromo-4-(trifluoromethyl)benzoic acid
581813-17-4

3-Bromo-4-(trifluoromethyl)benzoic acid synthesis

7synthesis methods
-

Yield:-

Steps:

Multi-step reaction with 4 steps
1: palladium 10% on activated carbon; hydrogen / methanol / 12 h / 20 °C / 775.74 Torr
2: sulfuric acid / water / Reflux
3: tert.-butylnitrite; copper(I) bromide / acetonitrile / 18 h / 0 - 25 °C
4: sodium hydroxide; water / 12 h / 25 °C

References:

MERCK SHARP & DOHME CORP.;MITCHELL, Helen;FRALEY, Mark E.;COOKE, Andrew J.;STUMP, Craig A.;ZHANG, Xu-Fang;MCCOMAS, Casey C.;SCHIRRIPA, Kathy;MCWHERTER, Melody;LIU, Chungsing;MAO, Qinghau WO2015/143653, 2015, A1

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