3-BroMoperylene synthesis
- Product Name:3-BroMoperylene
- CAS Number:23683-68-3
- Molecular formula:C20H11Br
- Molecular Weight:331.21
198-55-0
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23683-68-3
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Yield: 90%
Reaction Conditions:
with N-Bromosuccinimide in N,N-dimethyl-formamide at 20;
Steps:
Mixture of Brominated Perylenes
To a suspension of perylene (25.0 g, 100 mmol, 1 equiv) in DMF (1000 mL) a solution of NBS (23.0 g, 130 mmol, 1.3 equiv) in DMF (400 mL) was added via a syringe pump for 10 h. The obtained mixture was stirred overnight at r.t. and poured into water (2000 mL). The precipitate obtained was filtered off on a glass frit (G3) and was subsequently washed with EtOH (100 mL), Et2O (100 mL), and finally with CH2Cl2 (3 × 100 mL). The obtained solid was dried under vacuum, yielding a mixture of brominated perylenes; yield: 29.8 g (90%); 89% of 3-bromoperylene by GC-MS; yellow solid.
References:
Guzeev, Bogdan A.;Mladentsev, Dmitry Y.;Sharikov, Mikhail I.;Goryunov, Georgy P.;Uborsky, Dmitry V.;Voskoboynikov, Alexander Z. [Synthesis,2019,vol. 51,# 6,p. 1399 - 1407]
198-55-0
237 suppliers
$6.00/1g
23683-68-3
75 suppliers
$44.00/100mg