ChemicalBook CAS DataBase List 4-Bromomethyl-3-fluorophenylboronic acid,pinacol

4-Bromomethyl-3-fluorophenylboronic acid,pinacol synthesis

1synthesis methods

Product Name:4-Bromomethyl-3-fluorophenylboronic acid,pinacol
CAS Number:1150271-74-1
Molecular formula:C13H17BBrFO2
Molecular Weight:314.99

2-(3-FLUORO-4-METHYLPHENYL)-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE

903895-56-7
45 suppliers
$45.00/100mg

4-Bromomethyl-3-fluorophenylboronic acid,pinacol

1150271-74-1
44 suppliers
$33.00/100mg

Yield:1150271-74-1 76%

Reaction Conditions:

with N-Bromosuccinimide;2,2'-azobis(isobutyronitrile) in acetonitrile at 90; for 4 h;

References:

White, James R.;Price, Gareth J.;Schiffers, Stefanie;Raithby, Paul R.;Plucinski, Pawel K.;Frost, Christopher G. [Tetrahedron Letters,2010,vol. 51,# 30,p. 3913 - 3917] Location in patent:supporting information; experimental part