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ChemicalBook CAS DataBase List 4-(ChloroMethyl)-N-cyclopropylbenzaMide
873371-67-6

4-(ChloroMethyl)-N-cyclopropylbenzaMide synthesis

2synthesis methods
-

Yield:873371-67-6 95%

Reaction Conditions:

with N-ethyl-N,N-diisopropylamine in dichloromethane; for 1 h;

Steps:

A 4-Chloromethyl-N-cyclopropyl-benzamide

EXAMPLE A 4-Chloromethyl-N-cyclopropyl-benzamide 4-Chloromethyl-benzoyl chloride (2.82 g, 15 mmol) and cyclopropylamine (1.26 ml, 18 mmol) were reacted in CH2Cl2 (30 ml) and in the presence of Hünig's base (3.1 ml, 18 mmol) for 1 h. A precipitate was formed which was resolubilized by adding ethyl acetate. The reaction mixture was washed with a 5% KHSO4/10% K2SO4 solution, NaCl sat.

References:

US2007/37789,2007,A1 Location in patent:Page/Page column 9-10