4'-METHOXY-BIPHENYL-2-CARBALDEHYDE synthesis
- Product Name:4'-METHOXY-BIPHENYL-2-CARBALDEHYDE
- CAS Number:16064-04-3
- Molecular formula:C14H12O2
- Molecular Weight:212.24
104-92-7
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6630-33-7
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16064-04-3
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$201.66/0.5g
Yield:16064-04-3 349 mg
Reaction Conditions:
Stage #1: 1-bromo-4-methoxy-benzenewith Zn(OPiv)2*2LiCl;magnesium in tetrahydrofuran at 22; for 2 h;Inert atmosphere;
Stage #2: ortho-bromobenzaldehydewith [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(ll) dichloride in tetrahydrofuran at 25; for 1 h;Inert atmosphere;Negishi coupling reaction;
References:
Bernhardt, Sebastian;Manolikakes, Georg;Kunz, Thomas;Knochel, Paul [Angewandte Chemie - International Edition,2011,vol. 50,# 39,p. 9205 - 9209] Location in patent:supporting information; experimental part
5720-07-0
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6630-33-7
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16064-04-3
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$201.66/0.5g
104-92-7
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40138-16-7
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16064-04-3
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5720-07-0
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89-98-5
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16064-04-3
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104-92-7
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$10.00/10g
![2-Propanamine, N-[(2-methoxyphenyl)methylene]-2-methyl-](/CAS/20210305/GIF/82632-38-0.gif)
82632-38-0
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16064-04-3
37 suppliers
$201.66/0.5g