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ChemicalBook CAS DataBase List 4-(TRIFLUOROMETHYL)BENZOYL FLUORIDE
368-94-5

4-(TRIFLUOROMETHYL)BENZOYL FLUORIDE synthesis

10synthesis methods
14815-86-2 Synthesis
4-(trichloromethyl)benzoyl chloride

14815-86-2
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Yield:368-94-5 99.1%

Reaction Conditions:

with hydrogen fluoride at 70 - 90; under 7500.75 Torr; for 13.5 h;Autoclave;

Steps:

3.3

(3) 1000 g of trichloromethylbenzoyl chloride was injected into the autoclave, inhaled 2000 g of dry hydrogen fluoride, open stirring, and then slowly warming, 0.5 h heating to 70 ± 5 , holding 3 h, then heated to 90 ± 5 , holding for 10 h. The pressure during the reaction was 1.0 MPa. After cooling to 40 ° C, the pressure was released and the tail gas was absorbed with 25% sodium hydroxide to yield trifluoromethyl trifluoromethyl benzoyl fluoride in a yield of 99.1%.

References:

CN107400052,2017,A Location in patent:Paragraph 0017

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