Acetic acid, 2-[[[(phenylmethoxy)carbonyl]amino]oxy]- synthesis
1synthesis methods
- Product Name:Acetic acid, 2-[[[(phenylmethoxy)carbonyl]amino]oxy]-
- CAS Number:42989-82-2
- Molecular formula:C10H11NO5
- Molecular Weight:225.2
Yield:42989-82-2 74%
Reaction Conditions:
Stage #1: O-carboxymethylhydroxylamine hydrochloride;benzyl chloroformatewith sodium hydrogencarbonate in tetrahydrofuran;water at 0;
Stage #2: with sodium hydroxide in water;
Stage #3: with hydrogenchloride in water;
References:
Katritzky, Alan R.;Avan, Ilker;Tala, Srinivasa R. [Journal of Organic Chemistry,2009,vol. 74,# 22,p. 8690 - 8694] Location in patent:supporting information; experimental part