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502650-98-8

5-OXO-5-(3-TRIFLUOROMETHYLPHENYL)VALERIC ACID synthesis

1synthesis methods
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Yield:502650-98-8 27%

Reaction Conditions:

Stage #1: 1-bromo-3-(trifluoromethyl)benzenewith iodine;magnesium in tetrahydrofuran at 35; for 1.25 h;Inert atmosphere;Grignard Reaction;
Stage #2: dihydro-2H-pyran-2,6(3H)-dione in tetrahydrofuran at 0 - 20;Inert atmosphere;

References:

Awalt, Jon Kyle;Nguyen, Anh T.N.;Fyfe, Tim J.;Thai, Bui San;White, Paul J.;Christopoulos, Arthur;J?rg, Manuela;May, Lauren T.;Scammells, Peter J. [Journal of Medicinal Chemistry,2022,vol. 65,# 13,p. 9076 - 9095]

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