ChemicalBook CAS DataBase List ETHYL (S)-(+)-3-(2,2-DIMETHYL-1,3-DIOXOLAN-4-YL)-2-PROPENOATE

ETHYL (S)-(+)-3-(2,2-DIMETHYL-1,3-DIOXOLAN-4-YL)-2-PROPENOATE synthesis

14synthesis methods

Product Name:ETHYL (S)-(+)-3-(2,2-DIMETHYL-1,3-DIOXOLAN-4-YL)-2-PROPENOATE
CAS Number:64520-58-7
Molecular formula:C10H16O4
Molecular Weight:200.23

867-13-0
465 suppliers
$10.00/1g

1707-77-3 Synthesis

1,2:5,6-Bis-O-(1-methylethylidene)-D-mannitol

1707-77-3
358 suppliers
$5.00/5g

ETHYL (S)-(+)-3-(2,2-DIMETHYL-1,3-DIOXOLAN-4-YL)-2-PROPENOATE

64520-58-7
44 suppliers
$204.59/250mg

Yield:64520-58-7 98%

Reaction Conditions:

Stage #1: 1,2:5,6-di-O-isopropylidene-D-mannitolwith sodium periodate;sodium hydrogencarbonateInert atmosphere;
Stage #2: diethoxyphosphoryl-acetic acid ethyl esterwith potassium carbonate at 23;Inert atmosphere;Horner-Wadsworth-Emmons olefination;

References:

Wang, Yan;Dai, Wei-Min [Tetrahedron,2010,vol. 66,# 1,p. 187 - 196] Location in patent:supporting information; experimental part

867-13-0
465 suppliers
$10.00/1g

(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde

15186-48-8
320 suppliers
$8.00/5g

64520-58-7
44 suppliers
$204.59/250mg

References

L-Iditol, 1,2:5,6-bis-O-(1-methylethylidene)-

64870-23-1
1 suppliers
inquiry

311-46-6 Synthesis

311-46-6
161 suppliers
$9.00/10g

64520-58-7
44 suppliers
$204.59/250mg

References

867-13-0
465 suppliers
$10.00/1g

15186-48-8
320 suppliers
$8.00/5g

91926-90-8 Synthesis

(Z)-ETHYL-4,5-O-ISOPROPYLIDENE-(S)-4,5-DIHYDROXY-2-PENTENOATE

91926-90-8
44 suppliers
$40.00/1g

64520-58-7
44 suppliers
$204.59/250mg

References

1530-45-6 Synthesis

(Carbethoxymethyl)triphenylphosphonium bromide

1530-45-6
248 suppliers
$5.00/5g

2-Propenal, 3-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]-, (2E)-

4757-80-6
0 suppliers
inquiry

64520-58-7
44 suppliers
$204.59/250mg

791-28-6 Synthesis

791-28-6
484 suppliers
$6.00/25g

References

ETHYL (S)-(+)-3-(2,2-DIMETHYL-1,3-DIOXOLAN-4-YL)-2-PROPENOATE Related Search:

2-ETHOXY-3-BUTEN-1-OL