tetrakis(N-methyl-4-pyridiniumyl)porphine manganese(III) complex synthesis

Yield:-

Reaction Conditions:

with SO₂^(1-) in hydrogenchloride;Kinetics;byproducts: SO2; SO2(1-) radical generated by reaction with CO2(1-) or with the 2-hydroxy-2-propyl radical (these radicals were generated by radiolysis of isopropanol or CO2 containing acidic solns.), reaction in presence and absence of excess SO2; detn. by UV absorption;

References:

Neta, P.;Huie, Robert E.;Harriman, Anthony [Journal of Physical Chemistry,1987,vol. 91,# 6,p. 1606 - 1611]