2-Penten-1-ol, 2-methyl-5-[(1S,2R,4R)-2-methyl-3-methylenebicyclo[2.2.1]hept-2-yl]-, acetate, (2Z)- synthesis

3synthesis methods

Product Name:2-Penten-1-ol, 2-methyl-5-[(1S,2R,4R)-2-methyl-3-methylenebicyclo[2.2.1]hept-2-yl]-, acetate, (2Z)-
CAS Number:77-43-0
Molecular formula:C17H26O2
Molecular Weight:262.39

Bicyclo[2.2.1]heptane-2-propanal, 2-methyl-3-methylene-, (1S,2R,4R)-

131232-80-9
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2-Penten-1-ol, 2-methyl-5-[(1S,2R,4R)-2-methyl-3-methylenebicyclo[2.2.1]hept-2-yl]-, acetate, (2Z)-

77-43-0
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Yield:-

Steps:

Multi-step reaction with 3 steps
1: hexamethyleneimine benzoate / toluene / 3 h / Reflux
2: potassium acetate; triethylamine / 12 h / 80 °C
3: [Cp*Ru(cod)Cl][BF₄]; hydrogen; 2-butenedioic acid / acetone / 12 h / 60 °C / 3000.3 Torr

References:

Fehr, Charles;Magpantay, Iris;Vuagnoux, Magali;Dupau, Philippe [Chemistry - A European Journal,2011,vol. 17,# 4,p. 1257 - 1260]

2-Pentenal, 2-methyl-5-[(1S,2R,4R)-2-methyl-3-methylenebicyclo[2.2.1]hept-2-yl]-, (2E)-

1196993-37-9
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77-43-0
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References

77-42-9 Synthesis

[1S-[1alpha,2alpha(Z),4alpha]]-2-methyl-5-(2-methyl-3-methylenebicyclo[2.2.1]hept-2-yl)-2-penten-1-ol

77-42-9
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77-43-0
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References