ChemicalBook CAS DataBase List ACETIC ACID 9-DECEN-1-YL ESTER

ACETIC ACID 9-DECEN-1-YL ESTER synthesis

12synthesis methods

Product Name:ACETIC ACID 9-DECEN-1-YL ESTER
CAS Number:50816-18-7
Molecular formula:C12H22O2
Molecular Weight:198.3

By direct esterification of omega-Decenol, “Rosalva”(1.F.&F.).

13019-22-2 Synthesis

13019-22-2
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$13.00/5g

141-78-6 Synthesis

141-78-6
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$20.50/250ml

50816-18-7
54 suppliers
$101.00/5mL

Yield:50816-18-7 98%

Reaction Conditions:

with iodine for 2.5 h;Reflux;chemoselective reaction;

Steps:

2. Typical procedure for alcohol acetylation
General procedure: To a solution of benzyl alcohol (0.108 g, 1 mmol) in ethyl acetate (2 mL), iodine (0.1 mmol)was added and the mixture was heated at reflux for 2 h. When the reaction was complete(monitored by TLC), it was cooled and a saturated sodium thiosulfate solution (5 mL) was added. The reaction mixture was extracted with ethyl acetate (3x10 mL). The combined organiclayers were washed with brine, dried over anhydrous sodium sulphate and concentrated invacuo. The crude was then purified by column chromatography to give 1a in 97% yield (145mg, 0.97 mmol).

References:

Basumatary, Grace;Bez, Ghanashyam [Tetrahedron Letters,2017,vol. 58,# 45,p. 4312 - 4315] Location in patent:supporting information

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13019-22-2 Synthesis

13019-22-2
207 suppliers
$13.00/5g