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ChemicalBook CAS DataBase List ALLYLTRICHLOROGERMANE

ALLYLTRICHLOROGERMANE synthesis

10synthesis methods
24850-33-7 Synthesis
Allyltributyltin

24850-33-7
183 suppliers
$12.00/5g

10038-98-9 Synthesis
GERMANIUM(IV) CHLORIDE

10038-98-9
106 suppliers
$83.40/5g

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Yield:762-67-4 92%

Reaction Conditions:

in neat (no solvent);to a two-necked flask with N2 inlet introduced GeCl4; Sn-compound added dropwise at room temp. for about 5 min; stirred at 40°C for 3 h; flask attached to the vacuum line equipped with a trap, which cooled at -50°C to condense the product; product distilled by heating the reaction mixture up to 40°C;

References:

Horn, Anne;Mollendal, Harald;Demaison, Jean;Petitprez, Denis;Moreno, Juan Ramon Aviles;Benidar, Abdessamad;Guillemin, Jean-Claude [Journal of Physical Chemistry A,2005,vol. 109,# 17,p. 3822 - 3829]