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ChemicalBook CAS DataBase List amorphigenin

amorphigenin synthesis

3synthesis methods
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Yield:4208-09-7 33%

Reaction Conditions:

Stage #1: rotenonewith N-phenylselanylphthalimide;(1S)-10-camphorsulfonic acid;water in dichloromethane at 20; for 72 h;Inert atmosphere;Darkness;
Stage #2: with dihydrogen peroxide in pyridine;water at 0 - 20; for 2 h;

References:

Russell, David A.;Bridges, Hannah R.;Serreli, Riccardo;Kidd, Sarah L.;Mateu, Natalia;Osberger, Thomas J.;Sore, Hannah F.;Hirst, Judy;Spring, David R. [Journal of Natural Products,2020,vol. 83,# 6,p. 1829 - 1845]