ChemicalBook CAS DataBase List ANTIMONY(V) CHLORIDE

ANTIMONY(V) CHLORIDE synthesis

7synthesis methods

Product Name:ANTIMONY(V) CHLORIDE
CAS Number:7647-18-9
Molecular formula:Cl5Sb
Molecular Weight:299.02

7783-70-2
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7647-18-9
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$17.46/1G

Yield:-

Reaction Conditions:

with chloroform at 105; for 12 h;Reagent/catalyst;

Steps:

1; 2; 3; 4; 5 Example 1: Chlorination of SbF₅ by CHCb
In a 210 ml Hastelloy reactor, 10 g SbF₅ (0.046mol) and 54 g CHCb (0.046mol) were loaded. Then the reactor was heated to l05°C with agitation and agitated at l05°C for 12 hours. After that, the reactor was cooled with dry ice, and 100 ml de-ionized water (DI) was injected into the reactor. A gas sample from the vapor space was taken. Then the contents were transferred into a plastic bottle. The aqueous layer was analyzed by ion chromatography (IC). Results are shown in Table 1. IC analysis showed that CHCb can efficiently chlorinate SbF₅ to SbCb.

References:

THE CHEMOURS COMPANY FC, LLC;SUN, Xuehui;NAPPA, Mario Joseph;KRAUSE, Karl WO2020/51417, 2020, A2 Location in patent:Paragraph 0056-0065

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