ChemicalBook CAS DataBase List BENZYLTRIETHOXYSILANE

BENZYLTRIETHOXYSILANE synthesis

5synthesis methods

Product Name:BENZYLTRIETHOXYSILANE
CAS Number:2549-99-7
Molecular formula:C13H22O3Si
Molecular Weight:254.4

998-30-1
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$30.00/25 g

108-88-3
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$21.80/5 mL

2549-99-7
79 suppliers
$51.60/10 g

Yield:-

Reaction Conditions:

with 6Zr⁽⁴⁺⁾*6C₂₀H₁₂O₄^(2-)*8O^(2-)*4Cl^(1-)*4Co⁽²⁺⁾;sodium triethylborohydride in neat (no solvent) for 72 h;Inert atmosphere;Reflux;

Steps:

6 Regioselective Silylation with UiO-MOF-Co
General procedure: UiO-68-Co is also an active catalyst for regioselective silylation of benzylic C-H bonds without a directing group. See Table 8, below. The silylation reactions were performed with methylarenes (neat) and Et₃SiH under N₂at 100° C. catalyzed by 0.2 mol % UiO-68-Co. See Scheme 11, above. Only benzylic silylated products were obtained from p-Xylene and mesitylene in good yields.

References:

The University of Chicago;Lin, Wenbin;Manna, Kuntal;Ji, Pengfei US2018/361370, 2018, A1 Location in patent:Paragraph 0266-0267