Bicyclo[10.1.0]tridec-1-ene synthesis

1synthesis methods

Product Name:Bicyclo[10.1.0]tridec-1-ene
CAS Number:54766-91-5
Molecular formula:C13H22
Molecular Weight:178.31

Ethanamine, N-[(3,5-dichlorophenyl)methylene]-2,2-diethoxy-

1000210-73-0
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3105-35-9
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5601-67-2
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54766-91-5
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Yield:-

Reaction Conditions:

with zinc in N,N-dimethyl-formamide at 130; for 4 h;

Steps:

3.3-2.2
500 mg of the crude product of Step 1 and 2.5 mL of dimethylformamide Was added to a 25 mL round bottom flask and zinc powder 200 mg Was added at room temperature, and the mixture was stirred at 130 DEG C for 4 hours. The reaction was diluted with 200 mL of ethyl acetate, washed with brine (3 X 200 mL) And dried over anhydrous MgSO4. After filtering the residue, Mass spectrometry was performed under vacuum conditions to confirm the result (Step 2).

References:

Inje University Office research Affairs;KT&G Co., Ltd.;Jeong U-sik;Hong Sun-gi KR2018/119253, 2018, A Location in patent:Paragraph 0077; 0081-0083