bis(1-oxononyl) peroxide synthesis
- Product Name:bis(1-oxononyl) peroxide
- CAS Number:762-13-0
- Molecular formula:C18H34O4
- Molecular Weight:314.46
112-05-0
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Yield:-
Reaction Conditions:
with dmap;dihydrogen peroxide;dicyclohexyl-carbodiimide in dichloromethane at -15; for 1.5 h;
Steps:
(c) General procedure for synthesis of alkyl diacyl peroxides
General procedure: To a solution of DMAP (122 mg, 1.0 mmol) in CH2Cl2 (8 mL)(cooled to -15 ), 30%hydrogen peroxide (1.13 mL, 10 mmol) and DCC (2.06 g, 10 mmol) was added. The mixture wasvigorously stirred and the acid 3 (9 mmol) was then added. After being stirred for 1.5 hours at-15 , n-pentane (50 mL) was added into the reaction solutionand the resulting mixture wasfiltered by flash chromatography (n-pentane/ethylacetate = 10/1, 100 mL). The solution wasconcentrated on a rotary evaporator under vacuum at 10-15 give the peroxide 4.
References:
Jin, Can;Sun, Bin;Xu, Tengwei;Yan, Zhiyang;Zhang, Xun [Synlett,2019,vol. 30,# 13,p. 1585 - 1591] Location in patent:supporting information
764-85-2
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