Cyanomethyl methyl(4-pyridyl)carbamodithioate synthesis
- Product Name:Cyanomethyl methyl(4-pyridyl)carbamodithioate
- CAS Number:1158958-89-4
- Molecular formula:C9H9N3S2
- Molecular Weight:223.32
1121-58-0
180 suppliers
$20.00/1g
75-15-0
253 suppliers
$40.00/100g
590-17-0
334 suppliers
$5.00/5g
1158958-89-4
11 suppliers
$171.00/1g
Yield:1158958-89-4 59%
Reaction Conditions:
Stage #1: 4-(Methylamino)pyridinewith n-butyllithium in tetrahydrofuran at -10 - -7;
Stage #2: carbon disulfide in tetrahydrofuran at 0 - 20;
Stage #3: cyanomethyl bromide in tetrahydrofuran at 0 - 20;
References:
Benaglia, Massimo;Chiefari, John;Chong, Yen K.;Moad, Graeme;Rizzardo, Ezio;Thang, San H. [Journal of the American Chemical Society,2009,vol. 131,p. 6914 - 6915] Location in patent:supporting information; experimental part