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ChemicalBook CAS DataBase List D-149 Dye

D-149 Dye synthesis

5synthesis methods
-

Yield:-

Steps:

Multi-step reaction with 5 steps
1.1: sodium acetate; acetic acid / dichloromethane; water / 2 h / Reflux
2.1: sodium tetrahydroborate; acetic acid / 20 °C
3.1: tri-tert-butyl phosphine; potassium tert-butylate; palladium diacetate / 5,5-dimethyl-1,3-cyclohexadiene / 120 °C
4.1: trichlorophosphate / 10 °C
4.2: 20 °C
5.1: ammonium acetate; acetic acid / 120 °C

References:

Matsui, Masaki;Kotani, Masaya;Kubota, Yasuhiro;Funabiki, Kazumasa;Jin, Jiye;Yoshida, Tsukasa;Higashijima, Shinji;Miura, Hidetoshi [Dyes and Pigments,2011,vol. 91,# 2,p. 145 - 152]