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ChemicalBook CAS DataBase List Estradiol Cypionate
313-06-4

Estradiol Cypionate synthesis

2synthesis methods

To a solution of 2.5 grams (18.1 mmol) of potassium carbonate in 25 ml of water was added 225 ml of methanol followed by 5.0 grams (9.6 mmol) of estradiol 3,17β-dicyclopentanepropionate. The mixture was stirred for 2? hours at 202°C during which time some precipitation occurred. The mixture was poured into 700 ml of water with efficient stirring and the precipitated solid was removed by filtration, washed with water and dried.

Recrystallization of the crude product from 80% methanol gave 3.16 grams (83%) of estradiol 17β-cyclopentanepropionate(Estradiol Cypionate) melting at 148° to 151°C. Recrystallization from benzenepetroleum ether raised the MP to 151° to 152°C.

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Yield:-

Steps:

Multi-step reaction with 2 steps
1: pyridine
2: aqueous methanol. K2CO3

References:

Upjohn Co. US2611773, 1951, A

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