ETHYL 4-CHLOROBENZENESULFINATE synthesis
- Product Name:ETHYL 4-CHLOROBENZENESULFINATE
- CAS Number:13165-81-6
- Molecular formula:C8H9ClO2S
- Molecular Weight:204.67
Yield:13165-81-6 83%
Reaction Conditions:
with lithium perchlorate at 20; for 10 h;Electrochemical reaction;
Steps:
Electrochemical Synthesis of Sulfinic Esters 3 (Standard Conditions,Reaction Conditions A); General Procedure
General procedure: Thiophenol 1 (0.5 mmol), LiClO4 (53.2 mg, 0.5 mmol) and alcohol 2 (8mL) were sequentially added into a 25-mL three-necked flaskequipped with a platinum anode and cathode (plate, 1.0 cm × 1.0 cm).The reaction mixture was stirred at a constant current of 10 mA under air at ambient temperature. After completion of the reaction(monitored by TLC), the reaction mixture was purified by columnchromatography on silica gel (PE/EtOAc) to afford pure product 3.
References:
Zhou, Hongyan;Duan, Jiaokui;Xie, Dongtai;Yang, Jingya;Ma, Ben;Wang, Ganggang;Wu, Chengqi;Wang, Xi-Cun [Synthesis,2020,vol. 52,# 18,p. 2705 - 2712]
106-54-7
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