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ETHYL 4'-CYANOBIPHENYL-3-CARBOXYLATE synthesis

5synthesis methods
Benzoic acid, 3-[(methylsulfonyl)oxy]-, ethyl ester

1070663-96-5
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126747-14-6 Synthesis
4-Cyanophenylboronic acid

126747-14-6
391 suppliers
$6.00/1g

ETHYL 4'-CYANOBIPHENYL-3-CARBOXYLATE

131379-34-5
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Yield:131379-34-5 92%

Reaction Conditions:

with potassium phosphate;dicyclohexyl-(2′,4′,6′-triisopropyl-3,6-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine;palladium diacetate in tert-Amyl alcohol at 20 - 110;Inert atmosphere;Suzuki-Miyaura reaction;

References:

Bhayana, Brijesh;Fors, Brett P.;Buchwald, Stephen L. [Organic Letters,2009,vol. 11,# 17,p. 3954 - 3957] Location in patent:supporting information; experimental part

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