LITHIUM CYCLOHEXANEBUTYRATE synthesis
- Product Name:LITHIUM CYCLOHEXANEBUTYRATE
- CAS Number:62638-00-0
- Molecular formula:C10H17LiO2
- Molecular Weight:176.18
383-63-1
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62638-00-0
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210542-62-4
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Yield:210542-62-4 71%
Reaction Conditions:
Stage #1: lithium 4-cyclo-hexylbutyratewith lithium diisopropyl amide in tetrahydrofuran;cyclohexane at -20 - 20;
Stage #2: ethyl trifluoroacetate, in tetrahydrofuran;cyclohexane at -65; for 0.25 h;
Stage #3: with hydrogenchloride in tetrahydrofuran;cyclohexane;water;
References:
Reeves, Jonathan T.;Song, Jinhua J.;Tan, Zhulin;Lee, Heewon;Yee, Nathan K.;Senanayake, Chris H. [Journal of Organic Chemistry,2008,vol. 73,# 23,p. 9476 - 9478] Location in patent:supporting information; experimental part