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1065102-69-3

METHYL 2-(PYRIDIN-3-YL)OXAZOLE-4-CARBOXYLATE synthesis

2synthesis methods
500-22-1 Synthesis
3-Pyridinecarboxaldehyde

500-22-1
478 suppliers
$6.00/5g

5680-80-8 Synthesis
L-Serine methyl ester hydrochloride

5680-80-8
449 suppliers
$10.00/5g

METHYL 2-(PYRIDIN-3-YL)OXAZOLE-4-CARBOXYLATE

1065102-69-3
9 suppliers
$430.22/1g

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Yield:1065102-69-3 71%

Reaction Conditions:

Stage #1: 3-pyridinecarboxaldehyde;methyl (2S)-2-amino-3-hydroxypropanoate hydrochloridewith magnesium sulfate;triethylamine in tetrahydrofuran at 20; for 12 h;
Stage #2: with Bromotrichloromethane;1,8-diazabicyclo[5.4.0]undec-7-ene in dichloromethane at 0 - 20; for 12 h;

References:

Graham, Thomas H. [Organic Letters,2010,vol. 12,# 16,p. 3614 - 3617] Location in patent:supporting information; experimental part