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ChemicalBook CAS DataBase List N-Succinimidyl 6-maleimidohexanoate
55750-63-5

N-Succinimidyl 6-maleimidohexanoate synthesis

7synthesis methods
6066-82-6 Synthesis
N-Hydroxysuccinimide

6066-82-6
748 suppliers
$5.00/10g

55750-53-3 Synthesis
6-Maleimidocaproic acid

55750-53-3
317 suppliers
$9.00/1g

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Yield:55750-63-5 95%

Reaction Conditions:

with dicyclohexyl-carbodiimide in acetonitrile at 0 - 20;Inert atmosphere;

Steps:

2 Example 2Synthesis of Mc-OSu
Under nitrogen protection, 4.7 g (22 mmol) of MC and 25 g (22 mmol) of HOSu were added to 50 ml of acetonitrile.Another 4.5 g (22 mmol) of DCC was dissolved in 25 ml of acetonitrile,Keeping the internal temperature around 0°C,It was slowly dropped into the reaction solution.The reaction solution was reacted at 0°C for 2 hours and then reacted overnight at room temperature.filter,The filter cake was washed with acetonitrile 10ml×3.The filtrate was concentrated to dryness under reduced pressure.The resulting oil was dried under reduced pressure at room temperature for 6 h to give 6.4 g of light brown solid.Yield 95%.

References:

Sichuan Bai Li Pharmaceutical Co., Ltd.;Zhu Yi;Wang Yiqian;Zhuo Shi;Li Jie;Chen Lan;Wan Weili;Yu Yongguo CN107789630, 2018, A Location in patent:Paragraph 0064; 0065; 0066

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