pentacarbonylchloromanganese synthesis

6synthesis methods

Product Name:pentacarbonylchloromanganese
CAS Number:14100-30-2
Molecular formula:C5H10ClMnO5
Molecular Weight:240.521

10170-69-1 Synthesis

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Yield:14100-30-2 96%

Reaction Conditions:

with thionyl chloride in dichloromethane;Product distribution / selectivity;Inert atmosphere;

Steps:

Method (b) [5]; 1.08 g (2.76 mmol) of [Mn₂(CO)₁₀] was dissolved in 75 ml of dry CH₂Cl₂under nitrogen. 4 ml (0.048 mol) of SO₂Cl₂was then added fairly slowly (5-10 min). The system was allowed to react for 8 days, by which point some of the product had come out of solution and IR showed the reaction to be complete.The solvent was removed under vacuum and the remaining solid was washed several times with ethanol, and then dried under vacuum. 1.225 g of a yellow solid was obtained. The yield was 96%

References:

US2010/105770,2010,A1 Location in patent:Page/Page column 10

10170-69-1 Synthesis

10170-69-1
76 suppliers
$17.00/100mg

14100-30-2
2 suppliers
inquiry