![](/CAS/GIF/6217-22-7.gif)
PYRENE-4,5-QUINONE synthesis
- Product Name:PYRENE-4,5-QUINONE
- CAS Number:6217-22-7
- Molecular formula:C16H8O2
- Molecular Weight:232.23
![Pyrene](/CAS/GIF/129-00-0.gif)
129-00-0
324 suppliers
$9.00/1g
![PYRENE-4,5-QUINONE](/CAS/GIF/6217-22-7.gif)
6217-22-7
60 suppliers
$142.00/100mg
Yield: 85%
Reaction Conditions:
with tert.-butylhydroperoxide;Ru(2,4,13,15-tetraphenyl-1,5,12,16-tetraaza-tricyclo[14.2.2.06,11]eicosa-4,6(11),7,9,12-pentaene)Cl2 in acetonitrile for 6 h;Irradiation;Reagent/catalyst;
Steps:
2.4.2 General procedure for Sp2 C-H bond activation for polycyclic aromatic hydrocarbons
General procedure: To a solution of Zn(II)/Ru(II) complex (1.25μmol), pyrene (0.5mmol) and TBHP (1.0mmol) in 10mL of acetonitrile was added. After the reaction was stirred under visible light for 6h, (monitored the reaction by LC-MS) solvent was evaporated using rotavapor. Purification of the crude compounds by column chromatography with dichloromethane/ethyl acetate (9:1, v/v) as eluent to an afforded pure product.
References:
Gugulothu, Venkanna;Ahemed, Jakeer;Subburu, Mahesh;Yadagiri, Bhongiri;Mittal, Ritu;Prabhakar, Chetti;Pola, Someshwar [Polyhedron,2019,vol. 170,p. 412 - 423]
![Pyrene](/CAS/GIF/129-00-0.gif)
129-00-0
324 suppliers
$9.00/1g
![PYRENE-4,5,9,10-TETRONE](/CAS/20180703/GIF/14727-71-0.gif)
14727-71-0
74 suppliers
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![PYRENE-4,5-QUINONE](/CAS/GIF/6217-22-7.gif)
6217-22-7
60 suppliers
$142.00/100mg
![5-Formyl-4-phenanthroicacid](/CAS/GIF/5684-15-1.gif)
5684-15-1
7 suppliers
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![PYRENE-4,5-QUINONE](/CAS/GIF/6217-22-7.gif)
6217-22-7
60 suppliers
$142.00/100mg
![Phenanthrene-4,5-dicarboxylic acid](/CAS/GIF/5462-82-8.gif)
5462-82-8
14 suppliers
$53.20/250mg
![PYRENE-4,5-QUINONE](/CAS/GIF/6217-22-7.gif)
6217-22-7
60 suppliers
$142.00/100mg