![](/CAS/GIF/632-51-9.gif)
Tetraphenylethylene synthesis
- Product Name:Tetraphenylethylene
- CAS Number:632-51-9
- Molecular formula:C26H20
- Molecular Weight:332.44
![Styrene](/CAS/GIF/100-42-5.gif)
100-42-5
616 suppliers
$20.00/25mL
![Bromobenzene](/CAS/GIF/108-86-1.gif)
108-86-1
496 suppliers
$10.00/5g
![Tetraphenylethylene](/CAS/GIF/632-51-9.gif)
632-51-9
197 suppliers
$16.00/1g
Yield:632-51-9 98%
Reaction Conditions:
with iron(III) chloride hexahydrate;P(p-CH3OC6H4)3;sodium carbonate in N,N-dimethyl-formamide at 100; for 24 h;Reagent/catalyst;
Steps:
3.1.1. Classical procedure
General procedure: Procedure A: 0.025 mmol of catalyst, 0.05 mmol of ligand, and 3.125 mmol of base were introduced into a steel tube. Next, 2.5 mmol of halogenobenzene was added together with 2.25 mmol of styrene, and then 3 mL of the solvent was nally added. The steel reactor was placed in a thermostatic oil bath maintained at 100 °C for 24 h. After the reaction, the mixture was cooled and the organic phase was extracted three times with n-hexane or cyclohexane and then with the saturated NaCl solution. The adduct obtained was then dried using Na2SO4, filtered, and placed in a 25-mL ground ask. The solvent was evaporated using a rotary evaporator(Rotavapor). The final adduct was subjected to a TLC thin-layer chromatography test using n-hexane as an eluent and treated with silica gel column chromatography with the same eluent: n-hexane. Finally, the products obtained were analyzed using the usual analysis methods.
References:
Atoui, Dhiab;Sa?d, Khemais;Ben Salem, Ridha [Turkish Journal of Chemistry,2017,vol. 41,# 4,p. 587 - 600]
![Benzophenone](/CAS/GIF/119-61-9.gif)
119-61-9
779 suppliers
$5.00/10g
![Tetraphenylethylene](/CAS/GIF/632-51-9.gif)
632-51-9
197 suppliers
$16.00/1g
![Iodobenzene](/CAS/GIF/591-50-4.gif)
591-50-4
473 suppliers
$10.00/1g
![Diphenylacetylene](/CAS/GIF/501-65-5.gif)
501-65-5
212 suppliers
$16.00/5g
![Phenylboronic acid](/CAS/GIF/98-80-6.gif)
98-80-6
716 suppliers
$5.00/5g
![Tetraphenylethylene](/CAS/GIF/632-51-9.gif)
632-51-9
197 suppliers
$16.00/1g
![Styrene](/CAS/GIF/100-42-5.gif)
100-42-5
616 suppliers
$20.00/25mL
![Bromobenzene](/CAS/GIF/108-86-1.gif)
108-86-1
496 suppliers
$10.00/5g
![CIS-STILBENE](/CAS/GIF/645-49-8.gif)
645-49-8
133 suppliers
$21.89/1g
![TRANS-STILBENE](/CAS/GIF/103-30-0.gif)
103-30-0
180 suppliers
$9.00/5g
![Tetraphenylethylene](/CAS/GIF/632-51-9.gif)
632-51-9
197 suppliers
$16.00/1g