Trans-2-((trimethylsilyl)ethynyl)cyclohexanol synthesis
- Product Name:Trans-2-((trimethylsilyl)ethynyl)cyclohexanol
- CAS Number:142636-23-5
- Molecular formula:C11H20OSi
- Molecular Weight:196.36
Yield:142636-23-5 100%
Reaction Conditions:
Stage #1: trimethylsilylacetylenewith n-butyllithium in tetrahydrofuran;hexane at -78; for 0.166667 h;Inert atmosphere;
Stage #2: with boron trifluoride diethyl etherate in tetrahydrofuran;hexane at -78; for 0.166667 h;Inert atmosphere;
Stage #3: cyclohexane-1,2-epoxide in tetrahydrofuran;hexane at -78; for 0.5 h;Inert atmosphere;
References:
Jurberg, Igor Dias;Odabachian, Yann;Gagosz, Fabien [Journal of the American Chemical Society,2010,vol. 132,# 10,p. 3543 - 3552] Location in patent:supporting information; experimental part
54655-07-1
82 suppliers
$132.00/50ml
286-20-4
200 suppliers
$15.00/25g
142636-23-5
1 suppliers
inquiry