TRI-N-BUTYL(TRIMETHYLSILYLMETHYL)TIN synthesis
- Product Name:TRI-N-BUTYL(TRIMETHYLSILYLMETHYL)TIN
- CAS Number:77425-85-5
- Molecular formula:C16H38SiSn
- Molecular Weight:377.27
1461-22-9
205 suppliers
$10.00/10g
7439-95-4
8 suppliers
$8.19/0.9g
2344-80-1
289 suppliers
$15.00/1g
77425-85-5
22 suppliers
$893.30/5G
Yield:77425-85-5 95%
Reaction Conditions:
with iodine;ammonium chloride in diethyl ether;N2-atmosphere; addn. of Me3SiCH2Cl to Mg (activated with I2), refluxing(1 h), addn. of Bu3SnCl, refluxing (18 h); addn. of satd. aq. NH4Cl, extn. of aq. layer (ether), washing of org. layer (satd. aq. NaCl), drying (Na2SO4), evapn. of ether, distn. (vac.);
References:
Ager, David J.;Cooke, Glen E.;East, Michael B.;Mole, Susan J.;Rampersaud, Ashraff;Webb, Victoria J. [Organometallics,1986,vol. 5,# 9,p. 1906 - 1908]