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ChemicalBook CAS DataBase List Zirconium tetrachloride

Zirconium tetrachloride synthesis

8synthesis methods
Zirconium tetrachloride is obtained as an intermediate in recovering zirconium metal from zircon and other minerals (See Zirconium, Recovery). The tetrachloride is obtained by heating a mixture of zirconium hydroxide and car 1004 bon with chlorine gas
Also, tetrachloride can be made by reacting zirconium hydroxide with hydrochloric acid: Zr(OH)4 + 4HCl → ZrCl4 + 4H2O.
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Yield:-

Reaction Conditions:

with char coal in neat (no solvent);briquetting with a tenfold excess of char coal; heating the dry briquets at 600-650°C in stream of dry Cl2;; condensation of ZrCl4 in spherical condenser;;

References:

Plotnikov, V. A.;Gitman, E. B. [Zhurnal Prikladnoi Khimii,1946,vol. 19,p. 826 - 832] [Gmelin Handbuch der Anorganischen Chemie,Gmelin Handbook: Zr: MVol., 108, page 285 - 287]

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