cis-Cyclooctene
- CAS No.
- 931-88-4
- Chemical Name:
- cis-Cyclooctene
- Synonyms
- CYCLOOCTENE;CYCLOOCTENE 95%;Cyclooctene,99%;CIS-CYCLOOCTENE;Cyclooctene >CYCLOOCTENE, STANDARD FOR GC;cis-Cyclooctene ISO 9001:2015 REACH
- CBNumber:
- CB4193267
- Molecular Formula:
- C8H14
- Molecular Weight:
- 110.2
- MDL Number:
- MFCD00001753
- MOL File:
- 931-88-4.mol
Melting point | −16 °C(lit.) |
---|---|
Boiling point | 32-34 °C12 mm Hg(lit.) |
Density | 0.848 g/mL at 20 °C(lit.) |
refractive index |
n |
Flash point | 77 °F |
Water Solubility | Insoluble in water |
color | Colorless to Almost colorless |
BRN | 1901031 |
LogP | 3.930 |
CAS DataBase Reference | 931-88-4(CAS DataBase Reference) |
NIST Chemistry Reference | Cyclooctene(931-88-4) |
EPA Substance Registry System | Cyclooctene (931-88-4) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS02,GHS08 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H226-H304 | |||||||||
Precautionary statements | P210-P233-P240-P241-P301+P310-P331 | |||||||||
Hazard Codes | Xn | |||||||||
Risk Statements | 10-65 | |||||||||
Safety Statements | 29-33-62-16 | |||||||||
RIDADR | UN 3295 3/PG 3 | |||||||||
WGK Germany | 3 | |||||||||
HS Code | 2902.19.0050 | |||||||||
HazardClass | 3.2 | |||||||||
PackingGroup | III | |||||||||
NFPA 704 |
|
cis-Cyclooctene price More Price(8)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 29648 | Cyclooctene analytical standard | 931-88-4 | 1ml | $52.4 | 2022-05-15 | Buy |
TCI Chemical | C0506 | Cyclooctene >95.0%(GC) | 931-88-4 | 25mL | $50 | 2024-03-01 | Buy |
TCI Chemical | C0506 | Cyclooctene >95.0%(GC) | 931-88-4 | 500mL | $319 | 2024-03-01 | Buy |
Biosynth Carbosynth | FC164961 | Cyclooctene | 931-88-4 | 1kg | $550 | 2021-12-16 | Buy |
Biosynth Carbosynth | FC164961 | Cyclooctene | 931-88-4 | 2Kg | $1000 | 2021-12-16 | Buy |
cis-Cyclooctene Chemical Properties,Uses,Production
Purification Methods
The cis-isomer is freed from the trans-isomer by fractional distillation through a spinning-band column, followed by preparative gas chromatography on a Dowex 710-Chromosorb W GLC column. It is passed through a short alumina column immediately before use [Collman et al. J Am Chem Soc 108 2588 1986]. It has also been distilled in a dry N2 glove box from powdered fused NaOH through a Vigreux column (p 11), then passed through activated neutral alumina before use [Wong et al. J Am Chem Soc 109 4328 1987]. Alternatively it can be purified via the AgNO3 salt. This salt is obtained from crude cyclooctene (40 mL) by shaking at 70-80o with 50% w/w AgNO3 (2 x 15 mL) to remove cyclooctadienes (aqueous layer). Extraction is repeated at 40o (4 x 20 mL, of 50% AgNO3). Three layers are formed each time. The middle layer contains the AgNO3 adduct of cyclooctene which crystallises on cooling the layer to room temperature. The adduct (complex 2:1) is highly soluble in MeOH (at least 1g/mL) from which it crystallises in large flat needles when cooled at 0o. It is dried under slight vacuum for 1 week in the presence of CaCl2 and paraffin wax soaked in cyclooctene. It has m 51o and loses hydrocarbon on exposure to air. cis-Cyclooctene can be recovered by steam distillation of the salt, collected, dried (CaCl2) and distilled in vacuum. [Braude et al. J Chem Soc 4711 1957, AgNO3: Jones J Chem Soc 1808 1954, Cope & Estes J Am Chem Soc 72 1128 1950, Beilstein 5 I 35, 5 IV 263.] FLAMMABLE LIQUID.
cis-Cyclooctene Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 19368 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21687 | 55 |
career henan chemical co | +86-0371-86658258 15093356674; | factory@coreychem.com | China | 29826 | 58 |
Shaanxi Dideu Medichem Co. Ltd | +86-029-81138252 +86-18789408387 | 1057@dideu.com | China | 2392 | 58 |
Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9641 | 58 |
Shaanxi Dideu Medichem Co. Ltd | +86-029-89586680 +86-18192503167 | 1026@dideu.com | China | 9126 | 58 |
Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503259 +86-19930503259 | cherry@crovellbio.com | China | 18452 | 58 |
Shanghai Acmec Biochemical Technology Co., Ltd. | +undefined18621343501 | product@acmec-e.com | China | 33350 | 58 |
Aladdin Scientific | +1-+1(833)-552-7181 | sales@aladdinsci.com | United States | 57511 | 58 |
Mainchem Co., Ltd. | +86-0592-6210733 | sale@mainchem.com | China | 32360 | 55 |
View Lastest Price from cis-Cyclooctene manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2023-12-26 | cis-Cyclooctene
931-88-4
|
US $100.00-1.00 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | ||
2020-01-07 | Cyclooctene
931-88-4
|
US $1.00 / KG | 1KG | 99% | 20T | Shaanxi Dideu Medichem Co. Ltd | ||
2019-12-24 | cis-Cyclooctene
931-88-4
|
US $1.00 / KG | 1KG | 98%HPLC | 10t | Career Henan Chemical Co |
- cis-Cyclooctene
931-88-4
- US $100.00-1.00 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
- Cyclooctene
931-88-4
- US $1.00 / KG
- 99%
- Shaanxi Dideu Medichem Co. Ltd
- cis-Cyclooctene
931-88-4
- US $1.00 / KG
- 98%HPLC
- Career Henan Chemical Co
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