옥시브롬화인

옥시브롬화인
옥시브롬화인 구조식 이미지
카스 번호:
7789-59-5
한글명:
옥시브롬화인
동의어(한글):
옥시브롬화인;포스포로우수옥시브롬화물;포스포로우수옥시브롬화물(PHOSPHOROUSOXYBROMIDE)
상품명:
Phosphorus oxybromide
동의어(영문):
POBr3;phosphorus(v) oxybromide;Phosphoryl tribromide;PHOSPHOROUS OXYBROMIDE;PHOSPHORYL BROMIDE;phosphoryltribromide;AURORA KA-1088;Formylmelphalan;Phosphorictribromide;Phosphorus(V) oxybro
CBNumber:
CB5377198
분자식:
Br3OP
포뮬러 무게:
286.69
MOL 파일:
7789-59-5.mol
MSDS 파일:
SDS

옥시브롬화인 속성

녹는점
56 °C(lit.)
끓는 점
192 °C(lit.)
밀도
2.82 g/mL at 25 °C(lit.)
인화점
189°C
저장 조건
Store below +30°C.
용해도
reacts with H2O; soluble in benzene, ethyl ether,chloroform
물리적 상태
울퉁불퉁한 고체
Specific Gravity
2.822
색상
흰색에서 노란색으로
수용성
물에서 분해되다
감도
Moisture Sensitive
Merck
14,7348
InChIKey
UXCDUFKZSUBXGM-UHFFFAOYSA-N
CAS 데이터베이스
7789-59-5(CAS DataBase Reference)
NIST
Phosphorus tribromide oxide(7789-59-5)
EPA
Phosphoric tribromide (7789-59-5)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 C
위험 카페고리 넘버 14-34-37
안전지침서 26-36/37/39-43-45-7/8-Neverusewater.
유엔번호(UN No.) UN 1939 8/PG 2
WGK 독일 3
F 고인화성물질 10-21
위험 참고 사항 Corrosive
TSCA Yes
위험 등급 8
포장분류 II
HS 번호 28129090
유해 물질 데이터 7789-59-5(Hazardous Substances Data)
기존화학 물질 KE-28727
그림문자(GHS): GHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
예방조치문구:
P260 분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
NFPA 704
0
3 2
W

옥시브롬화인 C화학적 특성, 용도, 생산

화학적 성질

colorless to grey-brown crystals or fused mass

용도

Phosphorus(V) Oxybromide is a reagent used in the preparation of phosphoryl halide for N-protection of amino acids using group assisted purification (GAP). Phosphorus(V) Oxybromide is a brominating agent.

일반 설명

A colorless crystalline solid or liquid if heated above 133° F with a pungent odor. Phosphorus oxybromide is commonly heated and shipped in a molten state. Soluble in water, but, decomposed by water to hydrobromic and phosphoric acid with evolution of heat. Reacts with organic materials to cause fire. Evolves highly toxic and corrosive gases when exposed to fire. Corrosive to metals and tissue. Used to make other chemicals.

반응 프로필

Phosphorus oxybromide is incompatible with water, strong oxidizing agents, alcohols, bases, including amines. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

건강위험

CORROSIVE and/or TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Fire will produce irritating, corrosive and/or toxic gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Contact with molten substance may cause severe burns to skin and eyes. Runoff from fire control or dilution water may cause pollution.

화재위험

EXCEPT FOR ACETIC ANHYDRIDE (UN1715), THAT IS FLAMMABLE, some of these materials may burn, but none ignite readily. May ignite combustibles (wood, paper, oil, clothing, etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff. Flammable/toxic gases may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water. Substance may be transported in a molten form.

Safety Profile

Poison by ingestion, inhalation, and shin contact. A corrosive irritant to skin, eyes, and mucous membranes. A corrosive material. Reacts with steam, water to produce much heat with toxic fumes. When heated to decomposition it emits very toxic fumes of Brand POx. See also BROMIDES.

옥시브롬화인 준비 용품 및 원자재

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