ChemicalBook--->CAS DataBase List--->1752-30-3

1752-30-3

1752-30-3 Structure

1752-30-3 Structure
IdentificationMore
[Name]

Acetone thiosemicarbazone
[CAS]

1752-30-3
[Synonyms]

2-(1-METHYLETHYLIDENE)HYDRAZINECARBOTHIOAMIDE
ACETONE THIOSEMICARBAZIDE
ACETONE THIOSEMICARBAZONE
IFLAB-BB F0777-0579
2-(1-methylethylidene)-hydrazinecarbothioamid
acetonethiosemicarbazone[qr]
Acetonthiosemikarbazon
acetonthiosemikarbazon(czech)[qr]
ai3-22961[qr]
ATSC
Hydrazinecarbothioamide, 2-(1-methylethylidene)-
hydrazinecarbothioamide,2-(1-methylethylidene)-[qr]
Thiosemicarbazone acetone
thiosemicarbazoneacetone
thiosemicarbazoneacetone[qr]
ACETONE THIOSEMICARBAZONE (ATSC)
(Propan-2-ylideneamino)thiourea
1-(1-Methylethylidene)thiosemicarbazide
1-(Isopropylidene)thiosemicarbazide
1-Isopropylidenethiosemicarbazide
[EINECS(EC#)]

217-137-9
[Molecular Formula]

C4H9N3S
[MDL Number]

MFCD00022153
[Molecular Weight]

131.2
[MOL File]

1752-30-3.mol
Chemical PropertiesBack Directory
[Appearance]

Acetone thiosemicarbazide is a white to yellow crystalline solid
[Melting point ]

174-175°C
[Boiling point ]

213.8±23.0 °C(Predicted)
[density ]

1.142 (estimate)
[refractive index ]

1.5800 (estimate)
[solubility ]

soluble in Acetone
[form ]

powder to crystal
[pka]

12.20±0.70(Predicted)
[color ]

White to Light yellow
[InChIKey]

FQUDPIIGGVBZEQ-UHFFFAOYSA-N
[CAS DataBase Reference]

1752-30-3(CAS DataBase Reference)
[NIST Chemistry Reference]

2-(1-Methylethylidene)hydrazinecarbothioamide(1752-30-3)
[EPA Substance Registry System]

1752-30-3(EPA Substance)
Safety DataBack Directory
[Risk Statements ]

R21:Harmful in contact with skin.
R25:Toxic if swallowed.
R26:Very Toxic by inhalation.
[Safety Statements ]

S22:Do not breathe dust .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[RIDADR ]

2811
[RTECS ]

AL7350000
[HS Code ]

2930.90.9250
[HazardClass ]

6.1
[PackingGroup ]

I
[Hazardous Substances Data]

1752-30-3(Hazardous Substances Data)
[Toxicity]

mouse,LD50,intraperitoneal,23mg/kg (23mg/kg),BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD,Journal of Pharmacology and Experimental Therapeutics. Vol. 122, Pg. 110, 1958.
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

modified filling agent SBR-->preservative use for industry 1^<#^>-->acetone hydrazone-->subathizone
Hazard InformationBack Directory
[General Description]

Solid.
[Reactivity Profile]

ACETONE THIOSEMICARBAZIDE may form toxic gases with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. May form flammable gases with alkali metals. Explosive combination may occur with strong oxidizing agents, metal salts, peroxides, and sulfides. Emits toxic fumes of oxides of sulfur and nitrogen when heated to decomposition [Sax, 9th ed., 1996, p. 3165].
[Health Hazard]

High oral toxicity.
[Potential Exposure]

Acetone thiosemicarbazone is used as an intermediate in the manufacture of pharmaceuticals and pesticides. May be used as an agricultural chemical.
[Fire Hazard]

When heated to decomposition, ACETONE THIOSEMICARBAZIDE emits very toxic fumes of nitrogen oxides and sulfur oxides. Avoid decomposing heat.
[First aid]

Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In the case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy.
[Shipping]

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
[Incompatibilities]

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides
[Chemical Properties]

Acetone thiosemicarbazide is a white to yellow crystalline solid
[Waste Disposal]

It is inappropriate and possibly dangerous to the environment to dispose of expired or waste drugs and pharmaceuticals by flushing them down the toilet or discarding them to the trash. Household quantities of expired or waste pharmaceuticals may be mixed with wet cat litter or coffee grounds, double-bagged in plastic, discard in trash. Larger quantities shall carefully take into consideration applicable DEA, EPA, and FDA regulations. If possible return the pharmaceutical to the manufacturer for proper disposal being careful to properly label and securely package the material. Alternatively, the waste pharmaceutical shall be labeled, securely packaged and transported by a state licensed medical waste contractor to dispose by burial in a licensed hazardous or toxic waste landfill or incinerator.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-(1-Methylethylidene)hydrazinecarbothioamide(1752-30-3).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Acetone thiosemicarbazone(1752-30-3)MS
Acetone thiosemicarbazone(1752-30-3)1HNMR
Acetone thiosemicarbazone(1752-30-3)IR1
Acetone thiosemicarbazone(1752-30-3)IR2
Well-known Reagent Company Product InformationBack Directory
[TCI AMERICA]

Acetone Thiosemicarbazone,>97.0%(T)(1752-30-3)
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