ChemicalBook--->CAS DataBase List--->40499-83-0

40499-83-0

40499-83-0 Structure

40499-83-0 Structure
IdentificationMore
[Name]

3-Pyrrolidinol
[CAS]

40499-83-0
[Synonyms]

3-HYDROXYPYRROLIDINE
3-HYDROXYPYRROLINE
3-PYRROLIDINOL
DL-3-HYDROXYPYRROLIDINE
DL-3-PYRROLIDINOL
Pyrrolidin-3-ol
3-pyrrolidinol (DL)
3-PYRROLIDINOL FREE BASE
Pyrrolidine-3-ol
[EINECS(EC#)]

254-944-5
[Molecular Formula]

C4H9NO
[MDL Number]

MFCD00005256
[Molecular Weight]

87.12
[MOL File]

40499-83-0.mol
Chemical PropertiesBack Directory
[Boiling point ]

108-110 °C8 mm Hg(lit.)
[density ]

1.076 g/mL at 20 °C(lit.)
[refractive index ]

n20/D 1.49(lit.)
[Fp ]

>230 °F
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[form ]

Liquid
[pka]

14.91±0.20(Predicted)
[color ]

Clear colorless to yellow
[BRN ]

102542
[CAS DataBase Reference]

40499-83-0(CAS DataBase Reference)
[NIST Chemistry Reference]

3-Pyrrolidinol(40499-83-0)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37:Wear suitable gloves .
[WGK Germany ]

3
[F ]

10-34
[HS Code ]

29339900
Spectrum DetailBack Directory
[Spectrum Detail]

3-Pyrrolidinol(40499-83-0)1HNMR
3-Pyrrolidinol(40499-83-0)13CNMR
3-Pyrrolidinol(40499-83-0)IR1
3-Pyrrolidinol(40499-83-0)Raman
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

40499-83-0(sigmaaldrich)
[TCI AMERICA]

DL-3-Pyrrolidinol,>95.0%(GC)(T)(40499-83-0)
Hazard InformationBack Directory
[Purification Methods]

The (±)-isomer is purified by repeated distillation ( b 102-104o/12mm, 108-110o/18mm), and the (±)-picrate crystallises from EtOH with m 140-141o. The R(+)-enantiomer has b 70o/0.6mm and [] D +5.6o (c 3.63, MeOH). Its hydrochloride has a negative rotation and its dimethiodide has m 230o and [] 24 -8.02o. [Suyama & Kanno Yakugaku Zasshi (J Pharm Soc Japan) 85 531 1965, Uno et al. J Heterocycl Chem 24 1025 1987, Flanagan & Joullie Heterocycles 26 2247 1987, Beilstein 21 III/IV 44.]
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