| Identification | More | [Name]
2-Amino-4-nitro anisidine | [CAS]
99-59-2 | [Synonyms]
2-AMINO-1-METHOXY-4-NITROBENZENE
2-AMINO-4-NITRO ANISIDINE
2-AMINO-4-NITROANISOLE
2-METHOXY-5-NITROANILINE
2-METHOXY-5-NITRO-PHENYLAMINE
4-NITRO-2-AMINOANISOLE
4-NITRO-2-ANISIDINE
5-NITRO-O-ANISIDINE
Azoamine Scarlet K
AZOIC DIAZO COMPONENT 13
CI 37130
FAST SCARLET R BASE
FAST SCARLET SALT R
LAKE ORANGE G
SCARLET R BASE
SCARLET RC BASE
SCARLET R SALT
1-Amino-2-methoxy-5-nitrobenzene
1-Methoxy-2-amino-4-nitrobenzene
2-methoxy-5-nitro-anilin | [EINECS(EC#)]
202-770-5 | [Molecular Formula]
C7H10N3O3 | [MDL Number]
MFCD00007261 | [Molecular Weight]
184.17 | [MOL File]
99-59-2.mol |
| Chemical Properties | Back Directory | [Appearance]
5-Nitro-o-anisidine is an orange-red crystalline
compound. | [Melting point ]
117-119 °C(lit.) | [Boiling point ]
337.07°C (rough estimate) | [density ]
1.2068 | [vapor pressure ]
0.04Pa | [refractive index ]
1.6010 (estimate) | [Fp ]
119℃ | [solubility ]
382mg/L in organic solvents at 20 ℃ | [Colour Index ]
37130 | [pka]
2.42±0.10(Predicted) | [Stability:]
Stable, but may be moisture sensitive. Incompatible with water, acids, strong oxidizing agents, acid chlorides, acid anhydrides, chloroformates, liquid anisidine. | [Water Solubility ]
Slightly soluble. <0.01 g/100 mL at 19.5 ºC | [BRN ]
879620 | [LogP]
1.16 at 23℃ | [CAS DataBase Reference]
99-59-2(CAS DataBase Reference) | [IARC]
3 (Vol. 27, Sup 7) 1987 | [NIST Chemistry Reference]
Benzenamine, 2-methoxy-5-nitro-(99-59-2) | [EPA Substance Registry System]
99-59-2(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,Xn | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37:Wear suitable protective clothing and gloves . | [WGK Germany ]
2
| [RTECS ]
BZ7175000
| [Hazard Note ]
Irritant | [TSCA ]
Yes | [HS Code ]
2922290090 | [Safety Profile]
Suspected carcinogen
with experimental carcinogenic and
tumorigenic data. Moderately toxic by
ingestion. Mutation data reported. When
heated to decomposition it emits toxic
fumes of NOx. See also NITRO
COMPOUNDS OF AROMATIC
HYDROCARBONS. | [Hazardous Substances Data]
99-59-2(Hazardous Substances Data) |
| Hazard Information | Back Directory | [General Description]
Orange-red needles or orange powder. | [Reactivity Profile]
5-NITRO-O-ANISIDINE(99-59-2) is incompatible with strong oxidizing agents, acids, acid chlorides, acid anhydrides and chloroformates . | [Air & Water Reactions]
Insoluble in water. | [Potential Exposure]
5-Nitro-o-anisidine is a chemical intermediate
in the production of C.I. Pigment red 23, which is
used as a colorant for commodities, such as printing inks,
interior latex paints; lacquers, rubber, plastics, floor coverings;
paper coating; and textiles. It is also used with other
C.I. coupling components to produce various hues of red,
brown, yellow, and violet on cotton, silk, acetate and nylon. | [Fire Hazard]
Flash point data for this chemical are not available. 5-NITRO-O-ANISIDINE is probably combustible. | [First aid]
If this chemical gets into the eyes, remove any
contact lenses at once and irrigate immediately for at least
15 minutes, occasionally lifting upper and lower lids. Seek
medical attention immediately. If this chemical contacts the
skin, remove contaminated clothing and wash immediately
with soap and water. Seek medical attention immediately.
If this chemical has been inhaled, remove from exposure,
begin rescue breathing (using universal precautions, including
resuscitation mask) if breathing has stopped and CPR if
heart action has stopped. Transfer promptly to a medical
facility. When this chemical has been swallowed, get medical
attention. Give large quantities of water and induce
vomiting. Do not make an unconscious person vomit. | [Shipping]
UN3143 Dyes, solid, toxic, n.o.s. or Dye intermediates,
solid, toxic, n.o.s., Hazard Class: 6.1; Labels:
6.1-Poisonous materials, Technical Name Required. | [Incompatibilities]
Incompatible with oxidizers (chlorates,
nitrates, peroxides, permanganates, perchlorates, chlorine,
bromine, fluorine, etc.); contact may cause fires or explosions.
Keep away from alkaline materials, strong bases,
strong acids, oxoacids, epoxides, acid chlorides; acid anhydrides;
chloroformates. | [Chemical Properties]
5-Nitro-o-anisidine is an orange-red crystalline
compound. | [Chemical Properties]
orange to brown powder | [Waste Disposal]
Incineration (982℃, 2.0 seconds
minimum) with scrubbing for nitrogen oxides
abatement. | [Uses]
2-Methoxy-5-nitroaniline was used in the synthesis of 5-(9-acridinylamino)-p-anisidines via reaction with 9-anilinoacridines. It was also used in the synthesis of disazo disperse dyes containing nitro and methoxy groups, used for the dyeing of polyester fibre. | [Definition]
ChEBI: 2-methoxy-5-nitroaniline is a member of 4-nitroanisoles and a substituted aniline. | [Flammability and Explosibility]
Nonflammable |
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