2-Methyl-6-methylenoct-7-en-2-ol, Dihydroderivat

Dihydromyrcenol Struktur
53219-21-9
CAS-Nr.
53219-21-9
Bezeichnung:
2-Methyl-6-methylenoct-7-en-2-ol, Dihydroderivat
Englisch Name:
Dihydromyrcenol
Synonyma:
DIHYDROMERCENOL;Dihydrolaurenol;DITHDRO MYRCENOL;Dihydrop Myrcenol;DIHYDROMYRCENOL(SG);Dihydro myrcene alcohol;(R)-2,6-Dimethyl-7-octen-2-ol;2-Methyl-6-methylene-2-octanol;2-Methyl-6-methylideneoctan-2-ol;dihydromyrcenol dihydro derivative
CBNumber:
CB2161684
Summenformel:
C10H20O
Molgewicht:
156.27
MOL-Datei:
53219-21-9.mol

2-Methyl-6-methylenoct-7-en-2-ol, Dihydroderivat Eigenschaften

Siedepunkt:
91 °C(Press: 10 Torr)
Farbe
A colourless, somewhat viscous oil
CAS Datenbank
53219-21-9
EPA chemische Informationen
7-Octen-2-ol, 2-methyl-6-methylene-, dihydro deriv. (53219-21-9)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xi
R-Sätze: 36
S-Sätze: 26
Toxizität The acute oral LD50 in rats was reported as 3.6 g/kg (3.0-4.2 g/kg) (Mor eno, 1973). The acute dermal LD50 value in rabbits exceeded 5 g/kg (Moreno, 1973).
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
Sicherheit
P264 Nach Gebrauch gründlich waschen.
P264 Nach Gebrauch gründlich waschen.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P302+P352 BEI BERÜHRUNG MIT DER HAUT: Mit viel Wasser/... (Hersteller kann, falls zweckmäßig, ein Reinigungsmittel angeben oder, wenn Wasser eindeutig ungeeignet ist, ein alternatives Mittel empfehlen) waschen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.
P321 Besondere Behandlung
P332+P313 Bei Hautreizung: Ärztlichen Rat einholen/ärztliche Hilfe hinzuziehen.
P362 Kontaminierte Kleidung ausziehen und vor erneutem Tragen waschen.

2-Methyl-6-methylenoct-7-en-2-ol, Dihydroderivat Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

Dihydromyrcenol is a colorless liquid with a fresh citrus-like odor and a lavender note. It is obtained from 3,7-dimethyl-1,6- octadiene (citronellene), the pyrolysis product of cis-pinane and can be prepared by three different processes: (i) by addition of hydrogen chloride and subsequent hydrolysis of the resulting 2,6-dimethyl-2-chloro-7-octene; or (ii) by addition of formic acid and subsequent saponification of the resulting dihydromycrenyl formate; or (iii) by direct hydroxylation with 60–80% sulfuric acid.Dihydromyrcenol is used in fine fragrances as well as in soap and detergent perfumes for fresh lime and citrus-like floral notes.

Chemische Eigenschaften

Clear Colorless liquid, insoluble in water, soluble in 4-6 volumes of 55% ethanol or 1-2 volumes of 70% ethanol, also soluble in oily fragrances. The aroma is sweet and powerful, with fresh and spicy citrus, pine and cypress, lavender, fruity, floral, sweet and sour aromas, and has white lemon and cologne flavors.

Occurrence

Has apparently not been reported to occur in nature.

Verwenden

Dihydromyrcenol is an organic compound from the group of the acyclic terpenoidal alcohols. It is a fragrance with a powerful, fresh, lavender like, sweet citrus and floral fragrance, which is synthetically prepared. The pure substance appears as a colorless viscous liquid, which is practically insoluble in water.

synthetische

Dihydromyrcenol is prepared by addition of dihydromyrcene (generated from the cleavage of pinane, the hydrogenation product of pinene), with water and formic acid under acid catalysis.
By controlled, partial hydrogenation of myrcenol (Arctander, 1969).

2-Methyl-6-methylenoct-7-en-2-ol, Dihydroderivat Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


2-Methyl-6-methylenoct-7-en-2-ol, Dihydroderivat Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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53219-21-9(2-Methyl-6-methylenoct-7-en-2-ol, Dihydroderivat)Verwandte Suche:


  • DIHYDROMYRCENOL(SG)
  • DIHYDROMERCENOL
  • 2-Methyl-6-methylenoct-7-en-ol, Dihydroderivat
  • 2-Methyl-6-methylene-2-octanol
  • 2-Methyl-6-methylideneoctan-2-ol
  • (R)-2,6-Dimethyl-7-octen-2-ol
  • Dihydro myrcene alcohol
  • 7-Octen-2-ol,2-methyl-6-methylene-,dihydroderiv.
  • 2-methyl-6-methylene-7-octen-2-odihydroderiv.
  • Dihydromyrcenol2-Methyl-6-methylene-2-octanol
  • 2-methyl-6-methyleneoct-7-en-2-ol, dihydro derivative
  • Dihydrop Myrcenol
  • DITHDRO MYRCENOL
  • dihydromyrcenol dihydro derivative
  • Dihydrolaurenol
  • 53219-21-9
  • Aroma Chemicals
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