2',4'-Dihydroxyacetophenon

2,4-Dihydroxyacetophenone Struktur
89-84-9
CAS-Nr.
89-84-9
Bezeichnung:
2',4'-Dihydroxyacetophenon
Englisch Name:
2,4-Dihydroxyacetophenone
Synonyma:
1-(2,4-dihydroxyphenyl)ethanone;Ethanone, 1-(2,4-dihydroxyphenyl)-;RESACETOPHENONE;2,4-DHAP;HyMechroMone;NSC 37559;NSC 10883;AKOS 90593;Resoacetophenone;4-Acetoresorcinol
CBNumber:
CB4391766
Summenformel:
C8H8O3
Molgewicht:
152.15
MOL-Datei:
89-84-9.mol

2',4'-Dihydroxyacetophenon Eigenschaften

Schmelzpunkt:
143-144.5 °C(lit.)
Siedepunkt:
234.6°C (rough estimate)
Dichte
1.18 g/mL at 25 °C(lit.)
Brechungsindex
1.4945 (estimate)
storage temp. 
Inert atmosphere,Room Temperature
Löslichkeit
DMSO (Slightly), Methanol (Slightly)
pka
7.96±0.18(Predicted)
Aggregatzustand
Crystalline Powder or Crystals
Farbe
Off-white to pink to brown
PH
5 (1g/l, H2O, 20℃)
Sensitive 
Moisture Sensitive
Merck 
14,8140
BRN 
1282505
InChIKey
SULYEHHGGXARJS-UHFFFAOYSA-N
LogP
1.480 (est)
CAS Datenbank
89-84-9(CAS DataBase Reference)
NIST chemische Informationen
Ethanone, 1-(2,4-dihydroxyphenyl)-(89-84-9)
EPA chemische Informationen
Ethanone, 1-(2,4-dihydroxyphenyl)- (89-84-9)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xi
R-Sätze: 36/37/38
S-Sätze: 26-36-24/25
WGK Germany  2
RTECS-Nr. AM7525000
Hazard Note  Irritant
TSCA  Yes
HS Code  29145000
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
Sicherheit
P264 Nach Gebrauch gründlich waschen.
P264 Nach Gebrauch gründlich waschen.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.
P337+P313 Bei anhaltender Augenreizung: Ärztlichen Rat einholen/ärztliche Hilfe hinzuziehen.

2',4'-Dihydroxyacetophenon Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.

S-Sätze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S24/25:Berührung mit den Augen und der Haut vermeiden.

Chemische Eigenschaften

2,4-Dihydroxyacetophenone appears as a yellow-brown to reddish-brown fine crystalline powder. It slowly decomposes in water and can dissolve in hot alcohol, pyridine, and glacial acetic acid. In contrast, it is nearly insoluble in ether, benzene, and chloroform. A reaction with iron chloride causes it to adopt a red hue.

Verwenden

2,4-Dihydroxyacetophenone (cas# 89-84-9) is a compound useful in organic synthesis. It is also used as intermediate for pharmaceuticals. Reagent for iron as a 10% alcoholic solution. A red color is obtained with ferric ions in slightly acid solution: Cooper, Ind. Eng. Chem. Anal. Ed. 9, 334 (1937).

Definition

ChEBI: 2',4'-dihydroxyacetophenone is a dihydroxyacetophenone that is acetophenone carrying hydroxy substituents at positions 2' and 4'. It has a role as a plant metabolite. It is a member of resorcinols and a dihydroxyacetophenone.

synthetische

Preparation by reaction of acetic acid on resorcinol,
with zinc chloride (Nencki reaction) (94%)
with boron trifluoride
with Amberlite IR-120 (a cation exchange resin, sulfonic acid type) (87%)
with polyphosphoric acid (63%)
with 70% perchloric acid (33%).

Sicherheitsprofil

Moderately toxic by ingestion. Experimental reproductive effects. A severe eye irritant. When heated to decomposition it emits acrid smoke and irritating fumes.

Synthese

2,4-Dihydroxyacetophenone is obtained by the acetylation of resorcinol and acetic acid. In addition, it can also be obtained by reacting resorcinol with chloroacetyl or acetic anhydride in the presence of zinc chloride.

2',4'-Dihydroxyacetophenon Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


2',4'-Dihydroxyacetophenon Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 639)Lieferanten
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Shanghai Time Chemicals CO., Ltd.
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jack.li@time-chemicals.com China 1807 55

89-84-9(2',4'-Dihydroxyacetophenon)Verwandte Suche:


  • Resoacetophenone
  • Resorcinol, 4-acetyl-
  • 2,4-Dihydroxyacetoph
  • NSC 10883
  • NSC 37559
  • 4-Acetylresorcinol Resacetophenone
  • IMp. A (EP): 1,3-Dihydroxybenzene (Resorcinol)
  • IMp. B (EP): 7-Hydroxy-2-Methyl-4H-1-benzopyran-4-one
  • 2,4- twohydroxyAcetophenone
  • 2',4'-Dihydroxyacetophenone, 97+%
  • 2,4-Dihydroxy acetophenone (2-acetyl resorcinol)
  • 2"4"-DIHYDROXYACETOPHENONERESACETOPHENONE
  • 2',4'-Dihydroxyacetophenone 4-Acetylresorcinol 2,4-Dihydroxyacetophenone
  • 2,4-Dihydroxyacetophenone,99%
  • 2,4-DIHYDROXYACETOPHENONE extrapure
  • 1-Acetyl-2,4-dihydroxybenzene, 4-Acetylresorcinol, Resacetophenone
  • 2,4-Dihydroxylacetophenone
  • 2-Acetyl-1,5-benzenediol
  • 4-Acetoresorcinol
  • 2',4'-Dihydroxyacetophenone,98%
  • 2',4'-Dihydroxyacetophenone≥ 99% (HPLC)
  • 2,4-DIHYDROXY ACETPHENONE
  • 2',4'-DIHYDROXYACETOPHENONE
  • 2,4-DIHYDROXYACETOPHENONE
  • 1-ACETYL-2,4-DIHYDROXYBENZENE
  • AKOS BBS-00004294
  • AKOS 90593
  • 1-(2,4-dihydroxyphenyl)-ethanon
  • 1-(2,4-Dihydroxyphenyl)-ethanone
  • 1-Acetylbenzene-2,4-diol
  • 2’,4’-dihydroxy-acetophenon
  • 4-Acetyl-1,3-benzenediol
  • 4-acetyl-resorcino
  • Acetophenone, 2',4'-dihydroxy-
  • beta-Resacetophenone
  • b-Resacetophenone
  • 4-ACETYLRESORCINOL
  • 2,4-Dihydroxyacetophenone C8H8O3
  • 2',4'-Dihydroxyacetophenone >
  • High quality 2,4-Dihydroxyacetophenone
  • Resorcinol Impurity 3
  • 2,4-Dihydroxy-Acetophenone (Resacetophenone -99%)
  • 89-84-9 2,4-Dihydroxyacetophenone
  • 2,4-DIHYDROXY ACETOPHENONE For Synthesis
  • HyMechroMone
  • Ethanone, 1-(2,4-dihydroxyphenyl)-
  • 1-(2,4-dihydroxyphenyl)ethanone
  • RESACETOPHENONE
  • 2,4-DHAP
  • +C1Resacetophenone
  • 2',4'-Dihydroxyacetophenone
  • 89-84-9
  • 98-84-9
  • CH3COC6H3OH2
  • KETONE
  • Building Blocks
  • C7 to C8
  • Carbonyl Compounds
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