TETRAIODOPHTHALIC ANHYDRIDE
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- CAS-Nr.
- 632-80-4
- Englisch Name:
- TETRAIODOPHTHALIC ANHYDRIDE
- Synonyma:
- 3,4,5,6-Tetraiodophthalic anhydride;TETRAIODOPHTHALIC ANHYDRIDE;Phthalicanhydride,tetraiodo-;4,5,6,7-tetraiodo-3-isobenzofurandione;4,5,6,7-tetraiodo-2-benzofuran-1,3-dione;4,5,6,7-tetraiodoisobenzofuran-1,3-dione;4,5,6,7-tetraiodo-1,3-Isobenzofurandione;1,3-Isobenzofurandione,4,5,6,7-tetraiodo-;4,5,6,7-tetraiodoisobenzofuran-1,3-quinone
- CBNumber:
- CB6193948
- Summenformel:
- C8I4O3
- Molgewicht:
- 651.7
- MOL-Datei:
- 632-80-4.mol
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TETRAIODOPHTHALIC ANHYDRIDE Eigenschaften
Sicherheit
- Risiko- und Sicherheitserklärung
- Gefahreninformationscode (GHS)
| Bildanzeige (GHS) |
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| Alarmwort |
Warnung |
| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H302 |
Gesundheitsschädlich bei Verschlucken. |
Akute Toxizität oral |
Kategorie 4 |
Warnung |
![GHS hazard pictograms]() src="/GHS07.jpg" width="20" height="20" /> |
P264, P270, P301+P312, P330, P501 |
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| Sicherheit |
| P280 |
Schutzhandschuhe/Schutzkleidung/Augenschutz tragen. |
| P305+P351+P338 |
BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen. |
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TETRAIODOPHTHALIC ANHYDRIDE Chemische Eigenschaften,Einsatz,Produktion Methoden
synthetische
CAUTION: This reaction should be carried out in a well-ventilated hood. <br/>To a flask equipped with a mechanical stirrer and an air condenser topped with a tube leading to a gas trap is added 74.0 gm (0.5 mole) of phthalic anhydride, 162 gm (0.638 mole) of iodine, and 300 ml of 60% fuming sulfuric acid (1.84 moles). The flask is gently heated to 45-50°C, at which point the reaction commences. If the reaction becomes too vigorous it may be necessary to use a ice bath to lower the temperature to 40-50°C. The reaction mixture is eventually (4 hr) heated up to 65°C until all visible reaction has ceased. The reaction mixture is cooled to 10-20°C and an additional 81.0 gm (0.318 mole) of iodine is added and the reaction again slowly heated up to 65°C (1?hr) and again when the reaction ceases it is cooled. Another 27.0 gm (0.107 mole) of iodine is added and the reaction is again heated up to 65°C (1 hr). The flask is heated with an oil bath to a bath temperature of 175-180°C, at which point the sulfur trioxide and iodine fumes evolve. After about 2 hr, when the gaseous evolution ceases, the flask is cooled to about 60°C and the mxiture then poured into a beaker of water. The contents are allowed to stand overnight at room temperature, filtered, washed with two 50-ml portions of cone, sulfuric acid and then with three 100 ml portions of water. The light yellow crystalline product is put into a beaker containing 1 liter of water and 10 gm of sodium bisulfite in order to remove the last traces of free iodine. The aqueous solution is decanted, the product washed five times with ? liter of water, washed twice with 100 ml of acetone and then dried at 60°C to afford 260-268 gm (80-82%), m.p. 327-328°C.
TETRAIODOPHTHALIC ANHYDRIDE Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
TETRAIODOPHTHALIC ANHYDRIDE Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 52)Lieferanten
632-80-4()Verwandte Suche:
- 4,5,6,7-tetraiodoisobenzofuran-1,3-dione
- 4,5,6,7-tetraiodo-2-benzofuran-1,3-dione
- 4,5,6,7-tetraiodoisobenzofuran-1,3-quinone
- 4,5,6,7-tetraiodo-1,3-Isobenzofurandione
- 1,3-Isobenzofurandione,4,5,6,7-tetraiodo-
- 4,5,6,7-tetraiodo-3-isobenzofurandione
- Phthalicanhydride,tetraiodo-
- TETRAIODOPHTHALIC ANHYDRIDE
- 3,4,5,6-Tetraiodophthalic anhydride
- 632-80-4
- I4C6CO2O
- C8I4O3
