PHENYLMAGNESIUM BROMIDE

PHENYLMAGNESIUM BROMIDE Properties

Melting point	153-154 °C
Density	1.134 g/mL at 25 °C
Flash point	−40 °F
storage temp.	water-free area
solubility	Miscible with tetrahydrofuran.
form	Liquid
color	Yellow to brown
Specific Gravity	1.14
Water Solubility	reacts
Sensitive	Air & Moisture Sensitive
BRN	3588849
InChIKey	ANRQGKOBLBYXFM-UHFFFAOYSA-M
CAS DataBase Reference	100-58-3(CAS DataBase Reference)
EPA Substance Registry System	Magnesium, bromophenyl- (100-58-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS02,GHS05,GHS07

Signal word

Danger

Hazard statements

H225-H302-H314

Precautionary statements

P210-P233-P280-P301+P312-P303+P361+P353-P305+P351+P338

Hazard Codes

F+,C,F

Risk Statements

12-14-22-34-19-11-67-40-37

Safety Statements

16-26-36/37/39-45-33-29-7/8-6A-43B

RIDADR

UN 3399 4.3/PG 1

WGK Germany

1

F

1-3-10

TSCA

Yes

HazardClass

4.3

PackingGroup

II

HS Code

29319090

NFPA 704

	3
3		2
	W

PHENYLMAGNESIUM BROMIDE price More Price(33)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	331376	Phenylmagnesium bromide solution 1.0?M in THF	100-58-3	4X25ML	$87	2024-03-01	Buy
Sigma-Aldrich	171565	Phenylmagnesium bromide solution 3.0M in diethyl ether	100-58-3	50ml	$72.4	2024-03-01	Buy
Sigma-Aldrich	171565	Phenylmagnesium bromide solution 3.0?M in diethyl ether	100-58-3	4X25ML	$95	2024-03-01	Buy
Sigma-Aldrich	171565	Phenylmagnesium bromide solution 3.0M in diethyl ether	100-58-3	18l	$3280	2024-03-01	Buy
TCI Chemical	P2025	Phenylmagnesium Bromide (16% in Tetrahydrofuran, ca. 1mol/L)	100-58-3	250g	$153	2024-03-01	Buy

Product number	Packaging	Price	Buy
331376	4X25ML	$87	Buy
171565	50ml	$72.4	Buy
171565	4X25ML	$95	Buy
171565	18l	$3280	Buy
P2025	250g	$153	Buy

PHENYLMAGNESIUM BROMIDE Chemical Properties,Uses,Production

Reduction agent for preparation of metal carbonyl compound

In 1890, L.Mond found that when carbon monoxide was burned after being put through the active metal nickel powder, it emitted green light flame. After the resulting gas was cooled, he could obtain colorless liquid (melting point 298K, the boiling point of 316K); if this gas is flowed through a heated glass tube, then it can be seen that the metallic nickel was deposited on the wall. This gas is tetracarbonyl nickel Ni(CO)4. Since the 1960s, people have synthesized a hundreds kinds of such carbonyl compounds and their derivatives. Almost all of the transition metal can form such compounds. This kind of special complex formed through transition metal with carbon monoxide ligands is called metal carbonyls, otherwise known as carbonyl complexes. Metal carbonyl occupies an important position in both theoretical research and practical application in modern inorganic chemistry.
Preparation of metal carbonyl compound can usually via the following methods:
1. Direct synthesis. Most metal carbonyl complexes are prepared by direct combination between metal and carbon monoxide. However, the metal must be new reduction products, and is in a very activated state.
2. Reduction carbonylation effect at high pressure. Apply reducing agent under high pressure to enable the carbonylation reaction between the metal and carbonyl group with the major reducing agents mainly including hydrogen, active metals, phenylmagnesium bromide (C6H5MgBr) and so on.
3. With thermal decomposition or UV irradiation decomposition, we can obtain certain polynuclear carbonyl compounds.
4. Two different kinds of metal carbonyl compounds can interact with each other to give hetero-nuclear carbonyl compound.

Related chemical reaction

1. Phenylmagnesium bromide can react with ferric chloride to give the coupling product. Cyclopentadienyl magnesium bromide can react with ferric chloride to give ferrocene.
2. It can react with chromium trichloride in diethyl ether solution to generate dibenzenechromium.
3. Hexaphenyldilead can be used as the antioxidant of polyphenylene ether lubricant that can be produced from the reaction of lead chloride with phenyl lithium or phenyl magnesium bromide.
4. Take tetrahydrofuran as the solvent, have phenylmagnesium bromide reacted with germanium tetrachloride to obtain tetraphenyl germane.
5. It can be obtained through the low-temperature reaction between lead chloride and phenylmagnesium bromide (Or phenyllithium) in the presence of iodobenzene to derive tetraphenyl lead.
6. Sodium tetraphenylborate is mainly used for the determination of potassium ion, ammonium ion, rubidium ion and cesium ion. It can be obtained with the following process: phenylmagnesium bromide is interacted with boron trifluoride/diethyl ether to generate Tetraphenylboron magnesium bromide first. Evaporate the diethyl ether; add water and then used the calculated amount of sodium carbonate for treatment to obtain it.
The above information is edited by the chemicalbook of Dai Xiongfeng.

Chemical Properties

Clear light brown to brown solution when properly

Uses

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Uses

Phenylmagnesium Bromide is a reagent used in the preparation of arylcarbonimidic dichlorides via dichloroiodobenzene-mediated gem-dichlorination of aryl isonitriles.

Definition

ChEBI: Phenylmagnesium bromide is an arylmagnesium halide. It has a role as a Grignard reagent.

PHENYLMAGNESIUM BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

2-(Methanesulfonylamino)phenylboronic acid (S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole 2-Aminoethoxydiphenyl borate 9-Bromo-9-phenylfluorene (S)-(-)-α,α-Diphenyl-2-pyrrolidinemethanol

2-Phenylquinoline 2-Nitrophenylboronic acid Benzophenone imine Benzhydrol 1,2,4,5-tetraphenylbenzene

2-(DIPHENYLMETHYL)-QUINUCLIDIN-3-ONE pridinol METHYL BIPHENYL-2-CARBOXYLATE 2,7-Dibromo-9,9'-spiro-bifluorene 2-Bromo-9,9-diphenylfluorene

1-BROMO-8-PHENYLOCTANE 3-HYDROXY-3-PHENYL-PIPERIDINE

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PHENYLMAGNESIUM BROMIDE Suppliers

Global( 195)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Guanlang Biotechnology Co,.LTD	+8619930503252	daisy@crovellbio.com	China	5964	58
Beijing Cooperate Pharmaceutical Co.,Ltd	010-60279497	sales01@cooperate-pharm.com	CHINA	1811	55
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21689	55
Hangzhou FandaChem Co.,Ltd.	008657128800458; +8615858145714	fandachem@gmail.com	China	9341	55
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32686	60
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
SHANDONG ZHI SHANG CHEMICAL CO.LTD	+86 18953170293	sales@sdzschem.com	China	2931	58
Hebei Guanlang Biotechnology Co., Ltd.	+86-19930503282	alice@crovellbio.com	China	8822	58
Hubei xin bonus chemical co. LTD	86-13657291602	linda@hubeijusheng.com	CHINA	22968	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49391	58

Supplier	Advantage
Hebei Guanlang Biotechnology Co,.LTD	58
Beijing Cooperate Pharmaceutical Co.,Ltd	55
Henan Tianfu Chemical Co.,Ltd.	55
Hangzhou FandaChem Co.,Ltd.	55
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
SHANDONG ZHI SHANG CHEMICAL CO.LTD	58
Hebei Guanlang Biotechnology Co., Ltd.	58
Hubei xin bonus chemical co. LTD	58
CONIER CHEM AND PHARMA LIMITED	58

View Lastest Price from PHENYLMAGNESIUM BROMIDE manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-01-18	phenylmagnesium bromide 100-58-3	US $16.00 / KG	1600KG	99%	20T	Xiamen Wonderful Bio Technology Co., Ltd.
2023-07-26	PHENYLMAGNESIUM BROMIDE 100-58-3	US $10.00 / KG	1KG	99.%	10 ton	Hebei Guanlang Biotechnology Co,.LTD
2023-07-19	phenylmagnesium bromide 100-58-3	US $30.00 / KG	1KG	99%	20 Tons	Wuhan wingroup Pharmaceutical Co., Ltd

phenylmagnesium bromide
100-58-3
US $16.00 / KG
99%
Xiamen Wonderful Bio Technology Co., Ltd.

PHENYLMAGNESIUM BROMIDE
100-58-3
US $10.00 / KG
99.%
Hebei Guanlang Biotechnology Co,.LTD

phenylmagnesium bromide
100-58-3
US $30.00 / KG
99%
Wuhan wingroup Pharmaceutical Co., Ltd

PHENYLMAGNESIUM BROMIDE Spectrum

PHENYLMAGNESIUM BROMIDE(100-58-3)ESR

100-58-3(PHENYLMAGNESIUM BROMIDE)Related Search:

PHENYLMAGNESIUM CHLORIDE P-TOLYLMAGNESIUM BROMIDE PHENYLMAGNESIUM BROMIDE 4-CHLOROPHENYLMAGNESIUM BROMIDE 3-FLUOROPHENYLMAGNESIUM BROMIDE

4-Methoxyphenylmagnesium bromide O-TOLYLMAGNESIUM BROMIDE 2,4,6-TRIMETHYLPHENYLMAGNESIUM BROMIDE 4-FLUOROPHENYLMAGNESIUM BROMIDE 3,4-DIFLUOROPHENYLMAGNESIUM BROMIDE

Magnesium bromide hexahydrate Magnesium bromide Diethyl ether Benzene 2-Methyltetrahydrofuran

9-PHENANTHRYLMAGNESIUM BROMIDE 3 4 5-TRIFLUOROPHENYLMAGNESIUM BROMIDE PENTAFLUOROPHENYLMAGNESIUM BROMIDE

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