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ChemicalBook >> CAS DataBase List >>(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Structure
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT structure
CAS No.
415918-91-1
Chemical Name:
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
Synonyms
(S,R,R)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE;3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine;(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]aMine;(R)-2,2-Binaphthoyl-(S,S)-di(1-phenylethyl)aminoylphosphine;]dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct.;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]aMine, dichloroMethane adduct;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct,95%;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine,dichloromethaneadduct,min.95%;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95%
CBNumber:
CB1405194
Molecular Formula:
C36H30NO2P
Molecular Weight:
539.61
MDL Number:
MFCD04117687
MOL File:
415918-91-1.mol
MSDS File:
SDS
Last updated:2023-06-08 17:06:34
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(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Properties

Melting point 102-103 °C
Boiling point 710.7±63.0 °C(Predicted)
alpha +427° (c 0.83, CHCl3)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka -0.57±0.20(Predicted)
form Powder
color white
Sensitive moisture sensitive
CAS DataBase Reference 415918-91-1

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338
Hazard Codes  Xn
Risk Statements  36/37/38-22
Safety Statements  26-36/37/39
WGK Germany  3
HS Code  2934.99.4400

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical D4994 (R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine >98.0%(HPLC) 415918-91-1 200mg $174 2024-03-01 Buy
TCI Chemical D4994 (R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine >98.0%(HPLC) 415918-91-1 1g $531 2024-03-01 Buy
Strem Chemicals 15-1520 (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95% 415918-91-1 100mg $86 2024-03-01 Buy
Strem Chemicals 15-1520 (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95% 415918-91-1 500mg $335 2024-03-01 Buy
TRC D455833 (R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a'']dinaphthalen-4-yl)bis(1-phenylethyl)amine 415918-91-1 50mg $110 2021-12-16 Buy
Product number Packaging Price Buy
D4994 200mg $174 Buy
D4994 1g $531 Buy
15-1520 100mg $86 Buy
15-1520 500mg $335 Buy
D455833 50mg $110 Buy

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Chemical Properties,Uses,Production

Reactions

  • A ligand for asymmetric conjugate addition of dialkyl zinc reagents to activated olefins.
  • Ligand used in the iridium-catalyzed, enantioselective addition of nucleophiles to achiral
  • allylic esters.
  • Asymmetric hydrogenation.
  • Ir-catalyzed regio- and enantioselective Friedel-Crafts allylic alkylation of indoles.
  • Asymmetric hydrovinylation.
  • Used in 1,3-dipolar cycloaddition reactions of azomethine ylides and alkenes,9a and
  • Rh-catalyzed [5+2] cycloaddition of alkyne-vinyl-cyclopropanes.9b
  • Palladium-catalyzed enantioselective de-epimerization in catalytic asymmetric allylic alkylation.
  • Palladium-catalyzed enantioselective diamination of alkyl dienes.
Reactions of 415918-91-1

Uses

(R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a'']dinaphthalen-4-yl)bis(1-phenylethyl)amine (CAS# 415918-91-1) is an organic catalyst used in the stereoselective preparation of homoallylic nitriles.

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Preparation Products And Raw materials

Raw materials

Preparation Products

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Suppliers

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CONIER CHEM AND PHARMA LIMITED 		+8618523575427 sales@conier.com China 49391 58
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Supplier Advantage
CONIER CHEM AND PHARMA LIMITED 		58
Career Henan Chemica Co 		58
Dayang Chem (Hangzhou) Co.,Ltd. 		58
Hangzhou MolCore BioPharmatech Co.,Ltd. 		58
PT CHEM GROUP LIMITED 		58
GIHI CHEMICALS CO.,LIMITED 		58
Shaoxin Catsyn Co., Ltd. 		58
Suzhou Origin Specialty Chemicals Co., Ltd. 		58
Aladdin Scientific 		58
Suzhou Derivative Biotechnology Co., Ltd. 58

415918-91-1((S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT)Related Search:

BARIUM DINONYLNAPHTHALENESULFONATE (R)-MONOPHOS (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)[(1R)-1-PHENYLETHYL]AMINE (R)-N-(2-PROPYL)-1-PHENYLETHYLAMINE HYDROCHLORIDE
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (R)-MONOPHOS (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT (R)-(+)-N-BENZYL-1-PHENYLETHYLAMINE HYDROCHLORIDE (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
(R,R)-(+)-BIS(ALPHA-METHYLBENZYL)AMINE HYDROCHLORIDE (R,R)-(+)-BIS(ALPHA-METHYLBENZYL)AMINE HYDROCHLORIDE N N-BIS-[(R)-1-PHENYLETHYL]DIBENZO[D F][

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(S,R,R)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE 3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine,dichloromethaneadduct,min.95% (+)-N,N-Bis[(1R)-1-phenylethyl]-dinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-amine, (11bS) (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95% (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT (R)-2,2-Binaphthoyl-(S,S)-di(1-phenylethyl)aminoylphosphine (S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a 3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine 3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95% 3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]aMine 3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]aMine, dichloroMethane adduct R-(3,5-Dioxa-4-Phospha-Cyclohepta[2,1-A:3,4-A']Dinaphthalen-4-yl)Bis[(1R)-1-Phenylethyl]aMine 3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct,95% (11bR)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f] [1,3,2]dioxaphosphepin-4-amine ]dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct. (11bR)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f] [1,3,2]dioxaphosphepin-4-amine,99%e.e. (11bR)-N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N-bis[(1R)-1-phenylethyl]-, (11bR)- (3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine dichloromethane adduct (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT (11bR)-N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 415918-91-1 Privileged Ligands DSM MonoPhos Phosphoramidites Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents Chiral Phosphine CPN